Russian Journal of Inorganic Chemistry

, Volume 62, Issue 7, pp 893–899

Copper(II), nickel(II), and zinc(II) complexes with o-tozylaminobenzaldehyde 4,6-dimethylpyrimidyl hydrazone

  • L. D. Popov
  • V. V. Tkachev
  • Yu. P. Tupolova
  • S. A. Borodkin
  • G. V. Shilov
  • E. A. Ugolkova
  • O. I. Askalepova
  • A. S. Burlov
  • V. V. Lukov
  • I. N. Shcherbakov
  • S. I. Levchenkov
  • V. V. Minin
Coordination Compounds
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Abstract

o-Tosylaminobenzaldehyde dimethylpyrimidyl hydrazone and its copper(II), nickel(II), and zinc(II) complexesare synthesized and studied. According to the X-ray diffraction data, the zinc(II) complex has the structure of a tetragonal pyramid with the N3O donor ligand environment. According to EPR and magnetochemistry data, the copper(II) complex has a similar structure of the chelate core. In the nickel(II) complex, the solvent molecule completes the coordination core to an octahedron.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • L. D. Popov
    • 1
  • V. V. Tkachev
    • 2
  • Yu. P. Tupolova
    • 1
  • S. A. Borodkin
    • 1
  • G. V. Shilov
    • 2
  • E. A. Ugolkova
    • 3
  • O. I. Askalepova
    • 1
  • A. S. Burlov
    • 4
  • V. V. Lukov
    • 1
  • I. N. Shcherbakov
    • 1
  • S. I. Levchenkov
    • 5
  • V. V. Minin
    • 3
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Institute of Problems of Chemical PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  4. 4.Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-on-DonRussia
  5. 5.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia

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