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Cobalt(II) hexaiododimercurate(II) complex with ε-caprolactam: Synthesis and crystal structure

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Abstract

The conditions of synthesis of a new binary complex salt [Co(Cpl)6][Hg2I6] (Cpl is ε-caprolactam ε-C6H11NO) have been developed, and its structure has been characterized. The salt crystallizes in triclinic system, space group \(P\bar 1\) , a = 10.1078(4) Å, b = 12.2680(5) Å, c = 13.0782(5) Å, α = 62.872(2)°, β = 72.394(2)°, γ = 76.834(2)°, V = 1367.98(9) Å3, Z = 1, and ρcalc = 2.297 g/cm3. The structure is insular and consists of isolated ions.

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Authors and Affiliations

  1. Kuzbass State Technical University, ul. Vesennyaya 28, Kemerovo, 650000, Russia

    A. V. Tikhomirova & T. G. Cherkasova

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia

    I. Yu. Bagryanskaya

  3. Novosibirsk National Research State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    I. Yu. Bagryanskaya

  4. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    N. V. Pervukhina

Authors
  1. A. V. Tikhomirova
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  2. I. Yu. Bagryanskaya
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  3. N. V. Pervukhina
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  4. T. G. Cherkasova
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Corresponding author

Correspondence to T. G. Cherkasova.

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Original Russian Text © A.V. Tikhomirova, I.Yu. Bagryanskaya, N.V. Pervukhina, T.G. Cherkasova, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 2, pp. 193–196.

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Tikhomirova, A.V., Bagryanskaya, I.Y., Pervukhina, N.V. et al. Cobalt(II) hexaiododimercurate(II) complex with ε-caprolactam: Synthesis and crystal structure. Russ. J. Inorg. Chem. 62, 187–190 (2017). https://doi.org/10.1134/S0036023617020206

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  • DOI: https://doi.org/10.1134/S0036023617020206

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