Russian Journal of Inorganic Chemistry

, Volume 62, Issue 2, pp 191–196 | Cite as

Products of complexation in the Cu(CH3CОО)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide–salicylaldehyde–isopropanol system

  • A. V. Pulya
  • I. I. Seifullina
  • L. S. Skorokhod
  • N. N. Efimov
  • E. A. Ugolkova
  • V. G. Vlasenko
  • S. I. Levchenkov
  • A. L. Trigub
  • Ya. V. Zubavichus
  • V. V. Minin
Physical Methods of Investigation

Abstract

Copper(II) complexes isolated from the Cu(CH3COO)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide (Hydr)–salicylaldehyde (HSal)–isopropanol system [Cu2(HydrSal)2(μ-CH3COO)] (I), [Cu(HydrSal)2] (II) (HydrSal (hydrazone)is the condensation product of hydrazide and salicylaldehide) are synthesized and investigated. The complexes are characterized by elemental analysis, electrical conductivity measurements, and IR spectroscopy. The composition and structure of the Cu2+ coordination core are determined by ESR spectroscopy (I), magnetic susceptibility measurements and extended X-ray absorption fine structure (EXAFS) spectroscopy (II).

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • A. V. Pulya
    • 1
  • I. I. Seifullina
    • 1
  • L. S. Skorokhod
    • 1
  • N. N. Efimov
    • 2
  • E. A. Ugolkova
    • 2
  • V. G. Vlasenko
    • 3
  • S. I. Levchenkov
    • 4
  • A. L. Trigub
    • 5
  • Ya. V. Zubavichus
    • 5
  • V. V. Minin
    • 2
  1. 1.Mechnikov Odessa National UniversityOdessaUkraine
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Research Institute of PhysicsSouthern Federal UniversityRostov-on-DonRussia
  4. 4.Southern Research Center of the Russian Academy of SciencesRostov-on-DonRussia
  5. 5.Russian Research Center “Kurchatov Institute”MoscowRussia

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