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Structural features of monomeric octahedral d 2-rhenium(V) monooxo complexes with oxygen atoms of bidentate-chelating acido (O,O)-ligands

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Abstract

The structural features of 39 mononuclear octahedral d 2-rhenium(V) monooxo complexes (I–ХХХIХ) with oxygen atoms of bidentate-chelating (O,O) acido ligands (Lig) are considered. In 21 complexes (I–ХХI), the O(lig) atoms are both in trans and cis positions to oxo ligands. In the other 18 complexes (XXI–XXXIX), both O(lig) atoms are in cis positions to the O(oxo) ligands.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. S. Sergienko & A. V. Churakov

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  1. V. S. Sergienko
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  2. A. V. Churakov
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Correspondence to V. S. Sergienko.

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Sergienko, V.S., Churakov, A.V. Structural features of monomeric octahedral d 2-rhenium(V) monooxo complexes with oxygen atoms of bidentate-chelating acido (O,O)-ligands. Russ. J. Inorg. Chem. 61, 1708–1726 (2016). https://doi.org/10.1134/S0036023616140047

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  • DOI: https://doi.org/10.1134/S0036023616140047

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