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Phase states of Li(Na,K,Rb,Cs)/W/Mn/SiO2 composite catalysts for oxidative coupling of methane

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Abstract

This survey analyzes the results of studies into Li(Na,K,Rb,Cs)/W/Mn/SiO2 composites, which are used as catalysts for oxidative coupling of methane (OCM). The focus is on phase states. Our analysis shows that the SiO2 matrix is an active constituent of the composites and not an inert carrier of additives and the OCM heterogeneous process involves alkali-metal tungstate melts, along with polycrystalline manganese oxides. The effects of the cation ratio and synthetic routes on the phase composition of Li(Na,K,Rb,Cs)/W/Mn/SiO2 are assessed.

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References

  1. G. Olivier, Pat. US 1677363 (1928).

    Google Scholar 

  2. E. D. Bird, Pat. US 1656813 (1928).

    Google Scholar 

  3. H. L. Mitchell and R. H. Waghorne, Pat. US 4205194 (1980).

    Google Scholar 

  4. T. Fang and C. T. Yeh, J. Chin. Chem. Soc. 29, 265 (1981).

    Article  Google Scholar 

  5. G. F. Keller and M. Bhasin, J. Catal. 73 (1), 9 (1982).

    Article  CAS  Google Scholar 

  6. M. Baerns and W. Hinsen, Pat. DE 3237079 A1 (1983).

    Google Scholar 

  7. T. Ito and J. H. Lunsford, Nature 314, 721 (1985).

    Article  CAS  Google Scholar 

  8. V. S. Arutyunov and O. V. Krylov, Oxidative Conversions of Methane (Nauka, Moscow, 1998) [in Russian].

    Google Scholar 

  9. V. S. Arutynov and O. V. Krylov, Russ. Chem. Rev. 74, 1111 (2005).

    Article  CAS  Google Scholar 

  10. N. Ya. Usachev, V. V. Kharlamov, E. P. Belanova, et al., Russ._J. Gen. Chem. 79, 1252 (2009).

    Article  CAS  Google Scholar 

  11. V. S. Arutyunov, Oxidative Coupling of Natural Gas (Krasand, Moscow, 2011) [in Russian].

    Google Scholar 

  12. K. Khammona, S. Assabumrungrat, and W. Wiyarath, J. Eng. Appl. Sci. 7, 447 (2012).

    Google Scholar 

  13. Z. Mingsen, F. Yingjie, K. Li, et al., Petrochem. Tech. (China) 44, 401 (2015).

    Google Scholar 

  14. G. J. Hutching, M. S. Scurrell, and J. R. Woodhouse, Chem. Soc. Rev. 18, 251 (1989).

    Article  Google Scholar 

  15. U. Zavyalova, M. Holena, R. Schlögl, and M. Baerns, Chem. Cat. Chem. 3, 1935 (2011).

    CAS  Google Scholar 

  16. Z. Gholipour, A. Malekzadeh, M. Ghiasi, et al., Iran._J. Sci. Technol. 36 (A2), 189 (2012).

    CAS  Google Scholar 

  17. C. A. Jones, J. J. Leonard, and J. A. Sofranko, Pat. US 4443649 (1984).

    Google Scholar 

  18. C. A. Jones, J. J. Leonard, and J. A. Sofranko, Pat. US 4523049 (1985).

    Google Scholar 

  19. J. A. Sofranko, J. J. Leonard, and C. A. Jones, J. Catal. 103, 302 (1987).

    Article  CAS  Google Scholar 

  20. J. A. Sofranko, J. J. Leonard, and C. A. Jones, J. Catal. 103, 311 (1987).

    Article  Google Scholar 

  21. J. A. Sofranko, J. J. Leonard, C. A. Jones, et al., Catal. Today 3, 127 (1988).

    Article  CAS  Google Scholar 

  22. A. M. Gaffney, C. A. Jones, J. J. Leonard, et al., Stud. Surf. Sci. Catal. 38, 523 (1988).

    Article  Google Scholar 

  23. Kh. M. Minachev, N. Ya. Usachev, Yu. S. Khodakov, et al., Russ. Chem. Bull. 34, 1544 (1985).

    Article  Google Scholar 

  24. Kh. M. Minachev, N. Ya. Usachev, Yu. S. Khodakov, et al., Russ. Chem. Bull. 36, 456 (1987).

    Article  Google Scholar 

  25. Kh. M. Minachev, N. Ya. Usachev, Yu. S. Khodakov, et al., Russ. Chem. Bull. 36, 1975 (1987).

    Article  Google Scholar 

  26. R. Xu, W. Pang, J. Yu, Q. Huo, and J. Chen, Chemistry of Zeolites and Related Porous Materials: Synthesis and Structure (Wiley, Singapore, 2007).

    Book  Google Scholar 

  27. K. Otsuka, Q. Liu, M. Hatano, and A. Morikawa, Chem. Lett. 15, 903 (1986).

    Article  Google Scholar 

  28. K. Otsuka and T. Komatsu, J. Chem. Soc., Chem. Commun., No. 5, 388 (1987).

    Article  Google Scholar 

  29. R. Burch, G. D. Squide, and S. C. Tsang, Appl. Catal. 43, 105 (1988).

    Article  CAS  Google Scholar 

  30. S.-C. Kim, C.-S. Sunwoo, and E.-Y. Yu, Korean J. Chem. Eng. 7, 279 (1990).

    Article  CAS  Google Scholar 

  31. O. Y. Yan, Y. Wang, Y. S. Jin, and Y. Chen, Catal. Lett. 13, 221 (1992).

    Article  CAS  Google Scholar 

  32. X. Fang, S. Li, J. Lin, J. Gu, D. Yan, Fenzi Cuihua (J.Mol. Catal. (China)) 6, 255 (1992).

    CAS  Google Scholar 

  33. X. Fang, S. Li, J. Lin, and Y. Chu, Fenzi Cuihua (J.Mol. Catal. (China)) 6, 427 (1992).

    CAS  Google Scholar 

  34. Z. Jiang, X. Fang, C. Yu, and S. Li, Fenzi Cuihua (J.Mol. Catal. (China)) 6, 477 (1992).

    CAS  Google Scholar 

  35. Z. Jiang, X. Fang, C. Yu, and S. Li, Fenzi Cuihua (J.Mol. Catal. (China)) 6, 481 (1992).

    CAS  Google Scholar 

  36. Z. Jiang, X. Fang, C. Yu, and S. Li, Fenzi Cuihua (J.Mol. Catal. (China)) 6, 484 (1992).

    CAS  Google Scholar 

  37. J. H. Lunsford, Angew. Chem., Int. Ed. Engl. 34, 970 (1995).

    Article  CAS  Google Scholar 

  38. D. J. Wang, M. P. Rosynek, and J. H. Lunsford, J. Catal. 155, 390 (1995).

    Article  CAS  Google Scholar 

  39. M. P. Miguel, J. Coronas, M. Menéndez, and J. Santamaria, React. Kinet. Catal. Lett. 59, 277 (1996).

    Article  CAS  Google Scholar 

  40. A. Malekzadeh, A. Khododadi, M. Abedini, et al., Catal. Commun. 2 (8), 241 (2001).

    Article  CAS  Google Scholar 

  41. S. Pak, P. Qiu, and J. H. Lunsford, J. Catal. 179, 222 (1998).

    Article  CAS  Google Scholar 

  42. J. S. Ahari, R. Ahmadi, H. Mikami, et al., Catal. Today 145, 45 (2009).

    Article  CAS  Google Scholar 

  43. U. Simon, O. Görke, A. Berthold, et al., Chem. Eng. J. 168, 1352 (2011).

    Article  CAS  Google Scholar 

  44. A. Palermo, J. P. H. Varquez, A. F. Lee, et al., J. Catal. 177, 259 (1998).

    Article  CAS  Google Scholar 

  45. H. Liu, X. Wang, D. Yang, et al., J. Nat. Gas Chem. 17, 59 (2008).

    Article  Google Scholar 

  46. A. G. Dedov, G. D. Nipan, A. S. Loktev, et al., Appl. Catal. A: Gen. 406, 1 (2011).

    Article  CAS  Google Scholar 

  47. R. Chose, H. T. Hwang, and A. Varma, Appl. Catal. A: Gen. 452, 147 (2013).

    Article  CAS  Google Scholar 

  48. H. R. Bozorgzadeh, R. Ahmadi, M. M. Golkar, and M. R. Khodagholi, Petrol. Coal 53 (2), 84 (2011).

    CAS  Google Scholar 

  49. Y. T. Chua, A. R. Mohamed, and S. Bhatia, J. Chem. Technol. Biotechnol. 82 (1), 81 (2007).

    Article  Google Scholar 

  50. Y. T. Chua, A. R. Mohamed, and S. Bhatia, Appl. Catal. A: Gen. 343, 142 (2008).

    Article  CAS  Google Scholar 

  51. A. Palermo, J. P. H. Varquez, and R. M. Lambert, Catal. Lett. 68, 191 (2000).

    Article  CAS  Google Scholar 

  52. S. Ji, T. Xiao, S. Li, et al., J. Catal. 220, 47 (2003).

    Article  CAS  Google Scholar 

  53. S. Arndt, T. Otremba, U. Simon, et al., Appl. Catal. A: Gen. 425–426, 53 (2012).

    Article  CAS  Google Scholar 

  54. G. D. Nipan, A. G. Dedov, A. S. Loktev, et al., Dokl. Phys. Chem. 419, 73 (2008).

    Article  CAS  Google Scholar 

  55. A. A. Tyunyaev, G. D. Nipan, A. S. Loktev, et al., Russ. J. Inorg. Chem. 54, 664 (2009).

    Article  Google Scholar 

  56. A. Malekzadeh, M. Abedini, A. Khododadi, et al., Catal. Lett. 84, 45 (2002).

    Article  CAS  Google Scholar 

  57. J. Wu and S. Li, J. Phys. Chem. 99, 4566 (1995).

    Article  CAS  Google Scholar 

  58. S. Hou, Y. Cao, W. Xiong, et al., Ind. Eng. Chem. Res. 45, 7077 (2006).

    Article  CAS  Google Scholar 

  59. A. Malekzadeh, A. Khodadadi, A. K. Dalai, and M. Abedini, J. Nat. Gas Chem. 16, 121 (2007).

    Article  CAS  Google Scholar 

  60. J. Lin, J. Gu, D. Yang, et al., Petrochem. Technol. (China) 24, 293 (1995).

    Google Scholar 

  61. S. Li, J. Nat. Gas Chem. 12, 1 (2003).

    Google Scholar 

  62. K. Langfeld, B. Frank, V. E. Strempel, et al., Appl. Catal. A: Gen. 417–418, 145 (2012).

    Article  CAS  Google Scholar 

  63. Ye. K. Kazenas, Vaporization Thermodynamics of Double Oxides (Nauka, Moscow, 2004).

    Google Scholar 

  64. Ye. K. Kazenas and Y. V. Tsvetkov, Thermodynamics of Evaporation of Oxides (LKI, Moscow, 2008).

    Google Scholar 

  65. Z.-C. Jiang, C.-J. Yu, X.-P. Fang, et al., J. Phys. Chem. 97, 12870 (1993).

    Article  CAS  Google Scholar 

  66. J. Wu and S. Li, J. Nat. Gas Chem. 4, 91 (1995).

    CAS  Google Scholar 

  67. J. Wu and S. Li, J. Nat. Gas Chem. 4, 337 (1995).

    CAS  Google Scholar 

  68. X. Wang, J. Zhang, D. Yang, et al., Petrochem. Technol. (China) 26, 361 (1997).

    CAS  Google Scholar 

  69. S. Ji, S. Li, L. Gao, et al., Chinese J. Catal. 19, 526 (1998).

    CAS  Google Scholar 

  70. S. Ji, S. Li, B. Zhang, et al., Chinese J. Catal. 20, 608 (1999).

    CAS  Google Scholar 

  71. Y. Zhang, S. Li, G. Liu, et al., Nat. Gas Chem. Ind. (China), No. 4, 21 (1999).

    Google Scholar 

  72. H. Chen, J. Niu, B. Zhang, and S. Li, Chinese J. Catal. 21, 55 (2000).

    Google Scholar 

  73. S. Ji, S. Li, C. Xu, et al., J. Mol. Catal. (China) 14, 1 (2000).

    CAS  Google Scholar 

  74. S. Ji, S. Li, J. Xue, et al., J. Mol. Catal. (China) 14, 107 (2000).

    CAS  Google Scholar 

  75. S. Ji, S. Li, J. Zhao, and C. Xu, J. Chin. Electron Microsc. Soc. 19, 56 (2000).

    CAS  Google Scholar 

  76. S. B. Li, Chinese J. Chem. 19, 16 (2001).

    Article  CAS  Google Scholar 

  77. H. Chen, J. Niu, B. Zhang, and S. Li, Acta Phys.-Chim. Sin., 17 (2), 111 (2001).

    CAS  Google Scholar 

  78. H. Chen, J. Niu, B. Zhang, and S. Li, Chem. Res. in Chin. Univ. 22, 814 (2001).

    Google Scholar 

  79. S. Ji, S. Li, C. Xu, and J. Xue, J. Mol. Catal. (China) 16, 204 (2002).

    CAS  Google Scholar 

  80. S. Ji, S. Li, C. Xu, and J. Xue, J. Mol. Catal. (China) 16, 267 (2002).

    CAS  Google Scholar 

  81. L. Chou, Y. Cai, B. Zhang, J. Niu, et al., J. Chin. Chem. Soc. 51, 85 (2004).

    Article  CAS  Google Scholar 

  82. H. Liu, D. Yang, R. Gao, et al., Petrochem. Technol. (China), No. 2, 118 (2007).

    Google Scholar 

  83. X. Wang, L. Chou, B. Zhang, et al., J. Mol. Catal. (China) 20, 306 (2006).

    CAS  Google Scholar 

  84. S. Hou, W. Xiong, L. Liu, et al., Chin. J. Catal. 27, 678 (2006).

    CAS  Google Scholar 

  85. X. Wang, L. Chou, B. Zhang, et al., Nat. Gas Chem. Ind. (China), No. 2, 1 (2006).

    CAS  Google Scholar 

  86. J. Tang, S. Ji, K. Wang, and C. Li, Nat. Gas Chem. Ind. (China), No. 3, 19 (2009).

    Google Scholar 

  87. S. Ji, T. Xiao, S. Li, et al., Appl. Catal. A: Gen. 225, 271 (2002).

    Article  CAS  Google Scholar 

  88. U. Rodemerck, P. Ignaszewski, M. Lucas, and P. Claus, Chem. Eng. Technol. 23, 413 (2000).

    Article  CAS  Google Scholar 

  89. R. Koirala, R. Büchel, S. E. Pratsinis, and A. Baiker, Appl. Catal. A: Gen. 484, 97 (2014).

    Article  CAS  Google Scholar 

  90. S. Sadjadi, S. Jašo, H. R. Godini, et al., Catal. Sci. Technol. 5, 942 (2015).

    Article  CAS  Google Scholar 

  91. W. Zheng, D. Cheng, N. Zhu, et al., J. Nat. Gas Chem. 19, 15 (2010).

    Article  CAS  Google Scholar 

  92. F. Chen, W. Zheng, N. Zhu, et al., Catal. Lett. 125, 348 (2008).

    Article  CAS  Google Scholar 

  93. J. Wu, H. Zhang, S. Qin, and C. Hu, Appl. Catal. A: Gen. 323, 126 (2007).

    Article  CAS  Google Scholar 

  94. L. Zhao and S. P. Jiang, Nanostructures and Advanced Materials for Fuel Cells, Ed. by S. P. Jiang, and P. K. Shen (CRS Press, 2013).

  95. J. A. M. Van Roosmalen, P. Van Vlaaderen, and E. H. P. Cordfunke, J. Solid State Chem. 114, 516 (1995).

    Article  Google Scholar 

  96. S. M. K. Shahri and A. N. Pour, J. Nat. Gas Chem. 19, 47 (2010).

    Article  CAS  Google Scholar 

  97. Z. Q. Yu, X. M. Yang, J. H. Lunsford, and M. P. Rosynek, J. Catal. 154, 163 (1995).

    Article  CAS  Google Scholar 

  98. A. A. Greish, L. M. Glukhov, E. D. Finashina, et al., Mendeleev Commun. 20 (1), 28 (2010).

    Article  CAS  Google Scholar 

  99. I. Z. Ismagilov and E. V. Matus, S. D. Vasil’ev, et al., Kinet. Catal. 56, 456 (2015).

    Article  CAS  Google Scholar 

  100. N. Hiyoshi and T. Ikeda, Fuel Proc. Techn. 133, 29 (2015).

    Article  CAS  Google Scholar 

  101. S. Han, C. Bai, B. Zhang, et al., J. Solid State Chem. 237, 14 (2016).

    Article  CAS  Google Scholar 

  102. Zh. A. Kochkarov, M. V. Khubaeva, I. A. Shogenov, and Z. L. Khakulov, Russ. J. Inorg. Chem. 56, 946 (2011).

    Article  CAS  Google Scholar 

  103. S. Mahmoodi, M. R. Ehsani, and S. M. Ghoreisi, J. Ind. Eng. Chem. 16, 923 (2010).

    Article  CAS  Google Scholar 

  104. S. Mahmoodi, M. R. Ehsani, and M. Hamidzadeh, Iran. J. Chem. Chem. Eng. 30, 29 (2011).

    CAS  Google Scholar 

  105. A. Malekzadeh, A. K. Dalai, A. Khodadadi, and Y. Mortazavi, Catal. Commun. 9, 960 (2008).

    Article  CAS  Google Scholar 

  106. M. Yildiz, U. Simon, Y. Aksu, et al., Catal. Today 228, 5 (2014).

    Article  CAS  Google Scholar 

  107. T. W. Elkins and H. E. Hagelin-Weaver, Appl. Catal. A: Gen. 497, 96 (2015).

    Article  CAS  Google Scholar 

  108. T. Serres, C. Aquino, C. Miradatos, and Y. Schuurman, Appl. Catal. A: Gen. 504, 509 (2015).

    Article  CAS  Google Scholar 

  109. L. Olivier, S. Haag, H. Penemann, et al., Catal. Today 137, 80 (2008).

    Article  CAS  Google Scholar 

  110. G. D. Nipan, A. S. Loktev, K. V. Parkhomenko, et al., Dokl. Phys. Chem. 448, 19 (2013).

    Article  CAS  Google Scholar 

  111. G. D. Nipan, A. S. Loktev, K. V. Parkhomenko, et al., Russ. J. Inorg. Chem. 58, 887 (2013).

    Article  CAS  Google Scholar 

  112. J. Wang, L. Chou, B. Zhang, et al., J. Mol. Catal. A: Chem. 245, 272 (2006).

    Article  CAS  Google Scholar 

  113. A. G. Dedov, A. S. Loktev, G. D. Nipan, et al., Petrol. Chem. 55, 163 (2015).

    Article  CAS  Google Scholar 

  114. H. R. Godini and A. Gili, O. Görke, et al., Catal. Today 236, 12 (2014).

    Article  CAS  Google Scholar 

  115. H. Okamoto, J. Phase Equil. Diffusion 28, 309 (2007).

    Article  CAS  Google Scholar 

  116. G. D. Nipan, V. A. Artukh, V. S. Yusupov, et al., Dokl. Phys. Chem. 455, 60 (2014).

    Article  CAS  Google Scholar 

  117. G. D. Nipan, V. A. Artukh, V. S. Yusupov, et al., Inorg. Mater. 50, 912 (2014).

    Article  CAS  Google Scholar 

  118. V. Salehoun, A. Khodadadi, Y. Mortazavi, and A. Talebizadeh, Chem. Eng. Sci. 63, 4910 (2008).

    Article  CAS  Google Scholar 

  119. A. Talebzadeh, Y. Mortazavi, and A. A. Khodadadi, Fuel Proc. Technol. 90, 1319 (2009).

    Article  CAS  Google Scholar 

  120. M. R. Lee, M.-J. Park, W. Jeon, et al., Fuel Proc. Technol. 96, 175 (2012).

    Article  CAS  Google Scholar 

  121. S. M. K. Shahri and S. M. Alavi, J. Nat. Gas Chem. 18, 25 (2009).

    Article  CAS  Google Scholar 

  122. L. Chou, Y. Cai, B. Zhang, et al., J. Nat. Gas Chem. 11, 131 (2002).

    CAS  Google Scholar 

  123. S. V. Stevens, R. J. Hand, and J. H. Sharp, J. Mater. Sci. 32, 2929 (1997).

    Article  CAS  Google Scholar 

  124. I. G. Polyakova, Glass: Selected Properties and Crystallization (Walter De Gruyter Berlin/Boston, 197 (2014).

    Google Scholar 

  125. S. B. Holmquist, J. Am. Ceram. Soc. 44, 82 (1961).

    Article  Google Scholar 

  126. A. Romero-Serano, C. Gomez-Yañez, M. Hallen-Lopez, and J. Araujo-Osorio, J. Am. Ceram. Soc. 88, 141 (2005).

    Article  CAS  Google Scholar 

  127. P. S. Soares, Jr., E. D. Zanotto, V. M. Fokin, and H. Jain, J. Non-Cryst. Solids 331, 217 (2003).

    Article  CAS  Google Scholar 

  128. G. D. Nipan, Inorg. Mater. 50, 1012 (2014).

    Article  CAS  Google Scholar 

  129. G. D. Nipan, Inorg. Mater. 51, 389 (2015).

    Article  CAS  Google Scholar 

  130. S. Hou, Y. Cao, W. Xiong, et al., Chin. J. Catal. 27, 553 (2006).

    CAS  Google Scholar 

  131. S. Kirklin, M. K. Chan, L. Trahey, et al., Phys. Chem. Chem. Phys. 16, 22073 (2014).

    Article  CAS  Google Scholar 

  132. C. M. Julien, Solid State Ionics 177, 11 (2006).

    Article  CAS  Google Scholar 

  133. C. S. Johnson, J. Power Sources 165, 559 (2007).

    Article  CAS  Google Scholar 

  134. T. Tsuji, H. Umakoshi, and Y. Yamamura, J. Phys. Chem. Solids 66, 283 (2005).

    Article  CAS  Google Scholar 

  135. D. M. Cupid, T. Lehmann, T. Bergfeldt, et al., J. Mater. Sci. 48, 3395 (2013).

    Article  CAS  Google Scholar 

  136. G. A. Buzanov, G. D. Nipan, K. Yu. Zhizhin, and N. T. Kuznetsov, Doklady Chem. 465, 268 (2015).

    Article  CAS  Google Scholar 

  137. P. Lv, D. Chen, W. Li, et al., J. Alloys Compd. 460, 142 (2008).

    Article  CAS  Google Scholar 

  138. S. Ji, S. Li, Y. Liu, et al., J. Nat. Gas Chem. 8, 1 (1999).

    CAS  Google Scholar 

  139. C. H. Doh, A. Veluchamy, M. W. Oh, and B. C. Han, J. Electrochem. Sci. Technol. 2, 146 (2011).

    Article  CAS  Google Scholar 

  140. F. Yan, D. Chen, W. Li, et al., J. Alloys Compd. 458, 138 (2008).

    Article  CAS  Google Scholar 

  141. J. Wu, S. Li, J. Niu, and X. Fang, Appl. Catal. A: Gen. 124, 9 (1995).

    Article  CAS  Google Scholar 

  142. J. S. Ahari, M. T. Sadeghi, and S. Zarrinpashne, J. Nat. Gas Chem. 20, 204 (2011).

    Article  CAS  Google Scholar 

  143. J. S. Ahari, M. T. Sadeghi, and S. Z. Zarrinpashne, J. Taiwan Inst. Chem. Eng. 42, 751 (2011).

    Article  CAS  Google Scholar 

  144. B. Beck, V. Fleisher, S. Arndt, et al., Catal. Today 238, 212 (2014).

    Article  CAS  Google Scholar 

  145. L. Chou, Y. Cai, B. Zhang, et al., React. Kinet. Catal. Lett. 76, 311 (2002).

    Article  CAS  Google Scholar 

  146. C. H. Rüscher, K. R. Dey and T. Debhath, et al., J. Solid State Chem. 181, 90 (2008).

    Article  CAS  Google Scholar 

  147. A. N. Grundy, B. Hallstedt, L. J. Gauckler, et al., J. Phase Eq. 24, 21 (2003).

    CAS  Google Scholar 

  148. A. G. Dedov, V. A. Makhlin, M. V. Podlesnaya, et al., Theor. Found. Chem. Eng. 44, 1 (2010).

    Article  CAS  Google Scholar 

  149. V. I. Lomonosov, Yu. A. Gordienko, and M. Yu. Sinev, Kinet. Catal. 54, 451 (2013).

    Article  CAS  Google Scholar 

  150. K. Takanabe and E. Inglesia, J. Phys. Chem. 113, 10131 (2009).

    CAS  Google Scholar 

  151. G. Wozny and H. Arellano-Garsia, Chem. Eng. Trans. 21, 1399 (2010).

    Google Scholar 

  152. S. Sadjadi, U. Simon, H. R. Godini, et al., Chem. Eng. J. 281, 678 (2015).

    Article  CAS  Google Scholar 

  153. H. R. Godini and V. Fleischer, O. Görke, et al., Chem. Ing. Techn. 86, 1906 (2014).

    Article  CAS  Google Scholar 

  154. M. Daneshpayeh, A. Khodadadi, N. Mostoufi, et al., Fuel Process. Technol. 90, 403 (2009).

    Article  CAS  Google Scholar 

  155. S. Jašo, H. R. Godini, and H. Arellano-Garsia, Chem. Eng. Sci. 65, 6341 (2010).

    Article  CAS  Google Scholar 

  156. J. S. Ahari, S. Zarrinpashne, and M. T. Sadeghi, Fuel Process. Technol. 115, 79 (2013).

    Article  CAS  Google Scholar 

  157. S. Jašo, H. R. Godini, U. Simon, et al., J. Nat. Gas Chem. 21, 534 (2012).

    Article  CAS  Google Scholar 

  158. J. A. Langille, J. Pasale, J.-Y. Ren, et al., Chem. Eng. Sci. 61, 6637 (2006).

    Article  CAS  Google Scholar 

  159. H. R. Godini, H. Trivery, A. G. De Villasante, et al., Chem. Eng. Res. Des. 91, 2671 (2013).

    Article  CAS  Google Scholar 

  160. H. R. Godini and S. Xiao, M. Kim, et al., J. Ind. Eng. Chem. 20, 1993 (2014).

    Article  CAS  Google Scholar 

  161. M. Makri and C. G. Vayenas, Appl. Catal. A: Gen. 244, 301 (2003).

    Article  CAS  Google Scholar 

  162. W. Wang, S. Ji, D. Pan, and C. Li, Fuel Process. Technol. 92, 541 (2011).

    Article  CAS  Google Scholar 

  163. T. P. Tiemersma, A. S. Chaudhari, F. Gallucci, et al., Chem. Eng. Sci. 82, 232 (2012).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. D. Nipan, G. A. Buzanov, K. Yu. Zhizhin & N. T. Kuznetsov

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  1. G. D. Nipan
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  2. G. A. Buzanov
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  3. K. Yu. Zhizhin
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  4. N. T. Kuznetsov
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Correspondence to G. D. Nipan.

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Nipan, G.D., Buzanov, G.A., Zhizhin, K.Y. et al. Phase states of Li(Na,K,Rb,Cs)/W/Mn/SiO2 composite catalysts for oxidative coupling of methane. Russ. J. Inorg. Chem. 61, 1689–1707 (2016). https://doi.org/10.1134/S0036023616140035

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