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Effect of modification of the MF-4SC membranes in the potassium form with acid salts of heteropolyacids on membrane properties and characteristics of dp sensors based on them

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Hybrid materials based on perfluorinated sulfo cation-exchange MF-4SC membrane and nanoparticles of cesium hydrogen phosphotungstate and silicotungstate heteropolyanions were obtained. These membranes with a gradual dopant distribution along the length were used to develop potentiometric sensors for determination of amino-containing organic cations in aqueous solutions at pH < 7. A relationship between the membrane transport characteristics and sensing properties was elucidated.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    E. Yu. Safronova & A. B. Yaroslavtsev

  2. Voronezh State University, Universitetskaya pl. 1, Voronezh, 394893, Russia

    A. V. Parshina, E. A. Ryzhkova & O. V. Bobreshova

Authors
  1. E. Yu. Safronova
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  2. A. V. Parshina
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  3. E. A. Ryzhkova
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  4. O. V. Bobreshova
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  5. A. B. Yaroslavtsev
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Corresponding author

Correspondence to A. B. Yaroslavtsev.

Additional information

Original Russian Text © E.Yu. Safronova, A.V. Parshina, E.A. Ryzhkova, O.V. Bobreshova, A.B. Yaroslavtsev, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 12, pp. 1573–1578.

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Safronova, E.Y., Parshina, A.V., Ryzhkova, E.A. et al. Effect of modification of the MF-4SC membranes in the potassium form with acid salts of heteropolyacids on membrane properties and characteristics of dp sensors based on them. Russ. J. Inorg. Chem. 61, 1512–1517 (2016). https://doi.org/10.1134/S0036023616120159

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  • DOI: https://doi.org/10.1134/S0036023616120159

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