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Synthesis and study of ternary molybdates RbCaR(MoO4)3 with a scheelite-like structure in Rb2MoO4–CaMoO4–R2(MoO4)3 systems (R = Nd, Sm, Eu, Gd)

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Phase ratios in the subsolidus regions of Rb2MoO4–CaMoO4–R2(MoO4)3 systems (R = Nd, Sm, Eu, or Gd) were studied by vibrational spectroscopy, X-ray diffraction, and differential thermal analysis. Ternary molybdates RbCaR(MoO4)3 (R = Nd, Sm, Eu, Gd) with scheelite derivative structures (monoclinic symmetry system, space group P21/n) were synthesized. Unit cell parameters were determined, and IR and Raman spectra were characterized.

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References

  1. V. K. Trunov, V. A. Efremov, and Yu. A. Velikodnyi, Crystal Chemistry and Properties of Double Molybdates and Tungstates (Nauka, Leningrad, 1986) [in Russian].

    Google Scholar 

  2. N. M. Kozhevnikova and M. V. Mokhosoev, Triple Molybdates (Buryat State. Univ., Ulan-Ude, 2000) [in Russian].

    Google Scholar 

  3. N. M. Kozhevnikova, M. V. Mokhosoev, I. I. Murzakhanova, and F. P. Alekseev, Russ. J. Inorg. Chem. 35, 3157 (1990).

    CAS  Google Scholar 

  4. K. I. Petrov, M. E. Poloznikova, Kh. T. Sharipov, and V. V. Fomichev, Vibrational Spectra of Molybdates and Tunsgtates (Fan, Tashkent, 1990) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, ul. Sakh’yanovoi 8, Ulan-Ude, Republic of Buryatia, 670047, Russia

    N. M. Kozhevnikova

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  1. N. M. Kozhevnikova
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Correspondence to N. M. Kozhevnikova.

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Original Russian Text © N.M. Kozhevnikova, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 12, pp. 1579–1582.

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Kozhevnikova, N.M. Synthesis and study of ternary molybdates RbCaR(MoO4)3 with a scheelite-like structure in Rb2MoO4–CaMoO4–R2(MoO4)3 systems (R = Nd, Sm, Eu, Gd). Russ. J. Inorg. Chem. 61, 1518–1521 (2016). https://doi.org/10.1134/S0036023616120081

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  • DOI: https://doi.org/10.1134/S0036023616120081

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