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New copper(II), nickel(II), and cobalt(II) chelates derived from 2-methyl-3-{[3-methyl-5-oxo-1-phenylpyrazol-4- ylidene)methyl]amino}-quinazolin-4-one

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Abstract

Ligand system derived from pyrazolone-5 and N-aminoquinazolinone was prepared, its structure was studied. Metal chelates ML2 were prepared by reaction of the obtained ligand with copper(II), nickel(II), and cobalt(II) acetates. The complexes were studied by IR, electronic, and ESR spectroscopy, magnetochemistry, X-ray diffraction. Copper(II) complex was shown to have pseudo-tetrahedral structure, nickel(II) and cobalt(II) complexes are octahedral.

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References

  1. M. D. Mashkovskii, Therapeutic Agents (Novaya volna, Moscow, 2012) [in Russian].

    Google Scholar 

  2. Z.-G. Yu, W.-M. Ding, H.-R. Ji, and X.-Y. Zhu, Chin. J. Org. Chem. 30, 1358 (2010).

    CAS  Google Scholar 

  3. B. A. Omotowa and M. A. Mesubi, Appl. Organomet. Chem. 11, 1 (1997). doi 10.1002/(SICI)1099-0739(199701)

    Article  CAS  Google Scholar 

  4. M. Cushman, M. Jayaraman, J. A. Vroman, et al., J. Med. Chem. 43, 3665 (2000). doi 10.1021/jm000029d

    Article  Google Scholar 

  5. L. D. Popov, S. A. Borodkin, I. N. Shcherbakov, et al., Russ. J. Gen. Chem. 83, 1376 (2013). doi 10.1134/ S107036321307013X

    Article  CAS  Google Scholar 

  6. S. I. Levchenkov, I. N. Shcherbakov, L. D. Popov, et al., Russ. J. Struct. Chem. 56, 113 (2015).

    Article  CAS  Google Scholar 

  7. S. Kumar, G. Mishra, P. Singh et al., Chem. Sinica 2, 36 (2011).

    Google Scholar 

  8. A. K. Nanda, S. Ganduli, and R. Chakraborty, Molecules 12, 2413 (2007). doi 10.3390/12102413

    Article  CAS  Google Scholar 

  9. P. Panneerselvam, B. R. Ahmad, R. D. Sankar, and R.N. Kumar, Eur. J. Med. Chem. 44, 2328 (2009). doi 10.1016/jejmech.2008.04.010

    Article  CAS  Google Scholar 

  10. K. B. Gudasi, R. S. Vadavi, R. V. Shenoy, et al., Trans. Met. Chem. 30, 661 (2005). doi 10.1007/s11243-005-4829-1

    Article  CAS  Google Scholar 

  11. P. K. Shiva, K. L. Shiva, P. Melvin, et al., Biointerface Res. Appl. Chem. Open Access J. 1, 127 (2011).

    Google Scholar 

  12. K. S. Prasad, L. S. Kumar, S. Chandan, et al., Spectrochim. Acta A 81, 276 (2011). doi 10.1016/jsaa.2011.06. 010

    CAS  Google Scholar 

  13. K. B. Gudasi, R. S. Vadavi, R. V. Shenoy, et al., Transit. Met. Chem. 31, 135 (2006). doi 10.1007/s11243-005-6363-6

    Article  CAS  Google Scholar 

  14. G. M. Sheldrick, SHELXTL v. 6.14, Structure Determination Software Suite (Bruker AXS, Madison, Wisconsin, USA).

  15. U. Ewert, R. Stöber, G. Tomaschewski, and W. Freyer, Monatsh. Chem. 113, 973 (1982).

    Article  CAS  Google Scholar 

  16. A. A. Shklyaev, V. F. Anufrienko, and V. D. Ogorodnikov, Zh. Strukt. Khim. 14, 995 (1973).

    Google Scholar 

  17. A. I. Uraev, A. L. Nivorozhkin, G. I. Bondarenko, et al., Russ. Chem. Bull. 49, 1863 (2000).

    Article  CAS  Google Scholar 

  18. A. la Cour and A. Hazell, Acta Crystallogr., Sect. E 63, m330 (2007).

    Article  Google Scholar 

  19. A. B. P. Lever, Inorganic Electronic Spectroscopy (Elsevier, Amsterdam, 1984).

    Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Southern Federal University, pr. Stachki 194, Rostov-na-Donu, 344090, Russia

    L. D. Popov, G. I. Bondarenko, S. A. Borodkin, Yu. P. Tupolova, I. N. Shcherbakov, E. A. Raspopova & V. A. Kogan

  2. Institute of Problems in Chemical Physics, Russian Academy of Sciences, pr. Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Tkachev & G. V. Shilov

  3. Southern Scientific Center, Russian Academy of Sciences, ul. Chekhova 41, Rostov-na-Donu, 344006, Russia

    S. I. Levchenkov

  4. Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/3, Rostov-on-Don, 344104, Russia

    E. V. Korshunova

Authors
  1. L. D. Popov
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  2. G. I. Bondarenko
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  3. S. A. Borodkin
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  4. Yu. P. Tupolova
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  5. V. V. Tkachev
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  6. G. V. Shilov
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  7. S. I. Levchenkov
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  8. I. N. Shcherbakov
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  9. E. V. Korshunova
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  10. E. A. Raspopova
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  11. V. A. Kogan
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Corresponding author

Correspondence to L. D. Popov.

Additional information

Original Russian Text © L.D. Popov, G.I. Bondarenko, S.A. Borodkin, Yu.P. Tupolova, V.V. Tkachev, G.V. Shilov, S.I. Levchenkov, I.N. Shcherbakov, E.V. Korshunova, E.A. Raspopova, V.A. Kogan, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 5, pp. 603–610.

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Popov, L.D., Bondarenko, G.I., Borodkin, S.A. et al. New copper(II), nickel(II), and cobalt(II) chelates derived from 2-methyl-3-{[3-methyl-5-oxo-1-phenylpyrazol-4- ylidene)methyl]amino}-quinazolin-4-one. Russ. J. Inorg. Chem. 61, 575–582 (2016). https://doi.org/10.1134/S0036023616050181

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  • DOI: https://doi.org/10.1134/S0036023616050181

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