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Structure, oxygen non-stoichiometry, and phase transitions in Ca1–х Pr х MnO3–δ

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Manganites Ca1–х Pr х MnO3–δ, where 0 ≤ х ≤ 0.15 were studied. The compounds have orthorhombic structure (space group Pnma) at ambient temperature, which consecutively transforms on heating in air into phases with tetragonal I4/mcm and cubic 000000 structure. Increase in praseodymium concentration leads to higher phase transition temperatures, lower heat of structural transformations, more narrow homogeneity range of oxygen, and a wider temperature interval of tetragonal I4/mcm phase existence.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg, 620990, Russia

    I. A. Leonidov, E. I. Konstantinova, V. L. Kozhevnikov & R. F. Samigullina

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  1. I. A. Leonidov
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  2. E. I. Konstantinova
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  3. V. L. Kozhevnikov
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  4. R. F. Samigullina
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Correspondence to I. A. Leonidov.

Additional information

Original Russian Text © I.A. Leonidov, E.I. Konstantinova, V.L. Kozhevnikov, R.F. Samigullina, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 5, pp. 595–599.

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Leonidov, I.A., Konstantinova, E.I., Kozhevnikov, V.L. et al. Structure, oxygen non-stoichiometry, and phase transitions in Ca1–х Pr х MnO3–δ . Russ. J. Inorg. Chem. 61, 567–571 (2016). https://doi.org/10.1134/S0036023616050132

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  • DOI: https://doi.org/10.1134/S0036023616050132

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