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Synthesis of nanohydroxyapatite in the presence of iron(III) ions

Russian Journal of Inorganic Chemistry volume 61, pages 265–272 (2016)Cite this article

Abstract

The effect of small amounts of iron(III) ions on the morphology, phase composition, and structure of the products of the hydroxyapatite (HAP) synthesis has been studied by electron microscopy, X-ray powder diffraction, and Mossbauer spectroscopy methods. It has been demonstrated that the introduction of dopant iron(III) ions into the reaction mixture at different stages of HAP formation makes it possible to control crystal growth, morphology, and phase composition. The iron ions are not incorporated into the HAP crystal structure; rather, they form their proper nanophase, as well as adsorption clusters on the HAP surface.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    A. V. Severin & D. A. Pankratov

Authors
  1. A. V. Severin
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  2. D. A. Pankratov
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Correspondence to A. V. Severin.

Additional information

Original Russian Text © A.V. Severin, D.A. Pankratov, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 3, pp. 279-287.

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Severin, A.V., Pankratov, D.A. Synthesis of nanohydroxyapatite in the presence of iron(III) ions. Russ. J. Inorg. Chem. 61, 265–272 (2016). https://doi.org/10.1134/S0036023616030190

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  • DOI: https://doi.org/10.1134/S0036023616030190

Keywords

  • Calcium Sulfate
  • Iron Phosphate
  • Dopant Iron
  • Large Quadrupole Splitting
  • Calcium Sulfate Hemihydrate