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Crystal and molecular structure of the mercury dichloride complex with the macrocyclic dibenzo-aza-14-crown-4 ether ligand containing the embedded Di(α-pyridyl)bispidone fragment, [Hg(L)Cl2]

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Abstract

The crystal and molecular structure of [Hg(L)Cl2] (I), where L is dibenzo-aza-14-crown-4 ether with the embedded di(α-pyridyl)bispidone fragment, is studied by X-ray diffraction. The irregular five-vertex polyhedron of the Hg atom is formed by two Cl atoms and three N atoms of the dipyridylbispidone part of the L molecule. The O and N atoms of the macrocycle are not involved in metal coordination. The structure of complex I is compared with the structures of compounds [Zn(L)Cl2] · C2H5OH, [Co(L)(H2O)][CoCl4], and [Cu(L)(H2O)](ClO4) · 2H2O studied earlier.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. N. Polyakova, V. S. Sergienko & V. I. Sokol

  2. Peoples’ Friendship University of Russia, Moscow, Russia

    V. B. Kvartalov & N. M. Kolyadina

Authors
  1. I. N. Polyakova
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  2. V. S. Sergienko
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  3. V. B. Kvartalov
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  4. N. M. Kolyadina
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  5. V. I. Sokol
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Corresponding author

Correspondence to V. S. Sergienko.

Additional information

Original Russian Text © I.N. Polyakova, V.S. Sergienko, V.B. Kvartalov, N.M. Kolyadina, V.I. Sokol, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 2, pp. 180–185.

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Polyakova, I.N., Sergienko, V.S., Kvartalov, V.B. et al. Crystal and molecular structure of the mercury dichloride complex with the macrocyclic dibenzo-aza-14-crown-4 ether ligand containing the embedded Di(α-pyridyl)bispidone fragment, [Hg(L)Cl2]. Russ. J. Inorg. Chem. 61, 168–173 (2016). https://doi.org/10.1134/S0036023616020169

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  • DOI: https://doi.org/10.1134/S0036023616020169

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