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Electrochemical synthesis, structure, and photoluminescent properties of copper, zinc, and cadmium mixed-ligand complexes

  • Physical Methods of Investigation
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Abstract

Copper(II), zinc(II), and cadmium(II) mixed-ligand complexes [M(L)(L1)], (M = Cu (I), Cd (III)), [Zn(L)(L1)(H2O)] (II) and [Cd(L)(L2)] (IV)) on the basis of N-(2-{[1-phenyl-3-methyl-5-oxo-1,5-dihydro-4H-pyrazol-4-ylidene)methyl]amino}phenyl)-4-methylbenzenesulfonamide (H2L), 2-amino-1-ethylbenzimidazole (L1), and 2-aminopyrazine (L2) were prepared by electrochemical method. The composition and structure of the obtained compounds were proved by the data of C, H, N, S elemental analysis, IR and 1H NMR spectroscopy (for compounds II–IV), X-ray absorption spectroscopy (for compounds I and II), and magnetochemical measurements (for compound I), photoluminescent properties of complexes II–IV were also studied. The structure of compound II was determined by X-ray diffraction analysis.

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Authors and Affiliations

  1. Southern Scientific Center, Russian Academy of Sciences, ul. Chekhova 41, Rostov-na-Donu, 344006, Russia

    D. A. Garnovskii & S. I. Levchenkov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. S. Antsyshkina, G. G. Sadikov & V. S. Sergienko

  3. Research Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/3, Rostov-na-Donu, 344104, Russia

    D. A. Garnovskii, N. I. Makarova, A. I. Uraev & A. S. Burlov

  4. Research Institute of Physics, Southern Federal University, pr. Stachki 194, Rostov-na-Donu, 344090, Russia

    V. G. Vlasenko

  5. National Research Centre “Kurchatov Institute”, pl. Kurchatova 1, Moscow, 123182, Russia

    Ya. V. Zubavichus

Authors
  1. D. A. Garnovskii
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  2. A. S. Antsyshkina
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  3. N. I. Makarova
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  4. V. G. Vlasenko
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  5. G. G. Sadikov
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  6. V. S. Sergienko
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  7. Ya. V. Zubavichus
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  8. S. I. Levchenkov
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  9. A. I. Uraev
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  10. A. S. Burlov
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Corresponding author

Correspondence to D. A. Garnovskii.

Additional information

Original Russian Text © D.A. Garnovskii, A.S. Antsyshkina, N.I. Makarova, V.G. Vlasenko, G.G. Sadikov, V.S. Sergienko, Ya.V. Zubavichus, S.I. Levchenkov, A.I. Uraev, A.S. Burlov, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 12, pp. 1670–1678.

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Garnovskii, D.A., Antsyshkina, A.S., Makarova, N.I. et al. Electrochemical synthesis, structure, and photoluminescent properties of copper, zinc, and cadmium mixed-ligand complexes. Russ. J. Inorg. Chem. 60, 1528–1536 (2015). https://doi.org/10.1134/S0036023615120116

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  • DOI: https://doi.org/10.1134/S0036023615120116

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