Russian Journal of Inorganic Chemistry

, Volume 60, Issue 12, pp 1528–1536 | Cite as

Electrochemical synthesis, structure, and photoluminescent properties of copper, zinc, and cadmium mixed-ligand complexes

  • D. A. Garnovskii
  • A. S. Antsyshkina
  • N. I. Makarova
  • V. G. Vlasenko
  • G. G. Sadikov
  • V. S. Sergienko
  • Ya. V. Zubavichus
  • S. I. Levchenkov
  • A. I. Uraev
  • A. S. Burlov
Physical Methods of Investigation

Abstract

Copper(II), zinc(II), and cadmium(II) mixed-ligand complexes [M(L)(L1)], (M = Cu (I), Cd (III)), [Zn(L)(L1)(H2O)] (II) and [Cd(L)(L2)] (IV)) on the basis of N-(2-{[1-phenyl-3-methyl-5-oxo-1,5-dihydro-4H-pyrazol-4-ylidene)methyl]amino}phenyl)-4-methylbenzenesulfonamide (H2L), 2-amino-1-ethylbenzimidazole (L1), and 2-aminopyrazine (L2) were prepared by electrochemical method. The composition and structure of the obtained compounds were proved by the data of C, H, N, S elemental analysis, IR and 1H NMR spectroscopy (for compounds II–IV), X-ray absorption spectroscopy (for compounds I and II), and magnetochemical measurements (for compound I), photoluminescent properties of complexes II–IV were also studied. The structure of compound II was determined by X-ray diffraction analysis.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • D. A. Garnovskii
    • 1
    • 3
  • A. S. Antsyshkina
    • 2
  • N. I. Makarova
    • 3
  • V. G. Vlasenko
    • 4
  • G. G. Sadikov
    • 2
  • V. S. Sergienko
    • 2
  • Ya. V. Zubavichus
    • 5
  • S. I. Levchenkov
    • 1
  • A. I. Uraev
    • 3
  • A. S. Burlov
    • 3
  1. 1.Southern Scientific CenterRussian Academy of SciencesRostov-na-DonuRussia
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-na-DonuRussia
  4. 4.Research Institute of PhysicsSouthern Federal UniversityRostov-na-DonuRussia
  5. 5.National Research Centre “Kurchatov Institute”MoscowRussia

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