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Complexation of SnCl4 with salicylic aldehyde benzoyl hydrazone (H2Bs) and isonicotinoyl hydrazone (H2Is): Molecular and crystal structures of [SnCl3(HBs] and [SnCl3(Is · H] · 2CH3CN

  • XXVI International Chugaev Conference on Coordination Chemistry
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Abstract

Complexes [SnCl3(HBs)] (I) and [SnCl3(Is2H)] · nSolv (n = 2, Solv = CH3CN (II); n = 0 (III); n = 2, Solv = DMF (IV)) with the molar ratio Sn: ligand = 1: 1 are prepared by reacting SnCl4 with salicylic aldehyde benzoyl or isonicotinoyl hydrazone (H2Bs or H2Is). IR and 1H NMR spectroscopy proves that the ligands in I–IV are coordinated in a tridentate-cyclic mode through the azomethine nitrogen atom and the oxygen atoms of the oxy group (in I–IV) and the carbonyl (I) or oxyazine group (II–IV), so that the ligands in II–IV are in the N(py) protonated form. The thermal decomposition of complexes is found to be accompanied with the elimination of chlorine- and tin-containing species into vapor phase. The molecular and crystal structures of complexes I and II are determined by X-ray crystallography.

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References

  1. I. I. Seifullina, N. V. Shmatkova, and Z. A. Starikova, Russ. J. Inorg. Chem. 46, 1150 (2001).

    Google Scholar 

  2. I. I. Seifullina, N. V. Shmatkova, and Z. A. Starikova, Russ. J. Inorg. Chem. 49, 352 (2004).

    Google Scholar 

  3. I. I. Seifullina, N. V. Shmatkova, and Z. A. Starikova, Russ. J. Inorg. Chem. 50, 992 (2005).

    Google Scholar 

  4. I. I. Seifullina, N. V. Shmatkova, and E. E. Martsinko, Koord. Khim. 30, 228 (2004).

    Article  Google Scholar 

  5. I. I. Seifullina, N. Shmatkova, B. Galkin, and A. Nikitin, Poster Abstracts of the 7th International Symposium on Applied Bioinorganic Chemistry (Mexico, 2003), p. 96.

    Google Scholar 

  6. L. J. Rashan, A. A. Aziz, and K. D. Sulayman, As. J. Chem 10, 338 (1998).

    CAS  Google Scholar 

  7. R. Malhotra, S. Kumar, and K. S. Dhindsa, Ind. J. Chem. 4A, 321 (1997).

    Google Scholar 

  8. K. S. Prasad, L. S. Kumar, M. Prasad, and H. D. Revanasiddappa, http://dx.doi.org/10.1155/2010/854514.

  9. E. López-Torres, E. Torres, F. Zani, and M. A. Mendiola, J. Inorg. Biochem. 105, 600 (2011).

    Article  Google Scholar 

  10. A. Weissberger, E. Proskauer, J. Riddick, and E. Tups, Technique of Organic Chemistry, Vol. 7: Organic Solvents: Physical Properties and Methods of Purification (Interscience, New York, 1955; Inostrannaya Literatura, Moscow, 1961).

    Google Scholar 

  11. N. G. Klyuchnikov, A Manual of Inorganic Synthesis (Khimiya, Moscow, 1965) [in Russian].

    Google Scholar 

  12. F. W. Cheng, Microchem. J. 24, 989 (1959).

    Google Scholar 

  13. W. J. Gearly, Coord. Chem. Rev., No. 7, 81 (1971).

    Google Scholar 

  14. G. M. Sheldrick, SHELXTL PLUS, V5.10 (Bruker, 1997).

    Google Scholar 

  15. V. Gutman, Coordination Chemistry in Non-Aqueous Solutions (Springer, Vienna, 1968).

    Book  Google Scholar 

  16. Han Dong Yin, Min Hong, Gang Li, Da Qi Wang J. Organomet. Chem. 690, 3714 (2005).

    Article  CAS  Google Scholar 

  17. Min Hong, Han-Dong Yin, Shao-Wen Chen, Da-Qi Wang, J. Organomet. Chem. 695, 653 (2010).

    Article  CAS  Google Scholar 

  18. R. L. Dutta, Md. Hossain, and H. Munkir, J. Sci. Ind. Res. 44, 635 (1985).

    CAS  Google Scholar 

  19. J. D. Dunitz and H.-B. Buergi, Chapter on “Symmetry Aspects of Structure Correlation”, in Structure Correlation (Eds. H. B. Buergi and J. D. Dunitz) VCH Publishers, Weinheim, Germany, 1994. V. 2.

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Authors and Affiliations

  1. Odessa National University, Odessa, Ukraine

    N. V. Shmatkova & I. I. Seifullina

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. A. Korlyukov

Authors
  1. N. V. Shmatkova
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  2. I. I. Seifullina
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  3. A. A. Korlyukov
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Correspondence to N. V. Shmatkova.

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Original Russian Text © N.V. Shmatkova, I.I. Seifullina, A.A. Korlyukov, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 7, pp. 967–974.

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Shmatkova, N.V., Seifullina, I.I. & Korlyukov, A.A. Complexation of SnCl4 with salicylic aldehyde benzoyl hydrazone (H2Bs) and isonicotinoyl hydrazone (H2Is): Molecular and crystal structures of [SnCl3(HBs] and [SnCl3(Is · H] · 2CH3CN. Russ. J. Inorg. Chem. 60, 879–885 (2015). https://doi.org/10.1134/S0036023615070141

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  • DOI: https://doi.org/10.1134/S0036023615070141

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