Abstract
The possibility of obtaining films of substitutional solid solutions in a sulfide system via ionic exchange at the interface between the CdS film and the aqueous solution of a lead salt has been shown. The composition, structure, and morphology of freshly deposited films of CdS, PbS, and CdS layers held for 60–540 min at 353–368 K in an aqueous solution of lead acetate have been studied. It has been established by the methods of Raman spectroscopy (RS) and glancing-angle X-ray diffraction (GAXRD) that, due to ion-exchange processes, the formation of supersaturated substitutional solid solutions Cd x Pb1 − x S (x ≤ 0.31) occurs in the film, the cadmium content in which decreases gradually over the film thickness.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. S. Obaid, M. A. Mahdi, and Z. Hasson, Superlatt. Microstruct. 52, 816 (2012).
I. V. Malyar and S. V. Stetsyura, Semiconductors 45, 888 (2011).
P. M. Bethke and P. B. Barton, Am. Mineral. 56, 2034 (1971).
G. S. Oleinik, G. A. Mizetskaya, and A. I. Nizkova, Izv. Akad. Nauk SSSR, Neorg. Mater. 19, 1799 (1983).
L. N. Maskaeva, V. F. Markov, and G. A. Kitaev, Zh. Prikl. Khim. 73, 709 (2000).
M. A. Mohammed, A. M. Mousa, and J. P. Ponpon, J. Semicond. Technol. Sci 9, 117 (2009).
Z. I. Smirnova, L. N. Maskaeva, V. I. Voronin, and V. F. Markov, Butlerov. Soobshch. 21(7), 29 (2010).
L. N. Maskaeva, E. A. Dubinina, Kh. N. Mukhamedzyanov, and V. F. Markov, Butlerov. Soobshch. 27(15), 65 (2011).
L. N. Maskaeva, V. F. Markov, and A. A. Moskaleva, Butlerov. Soobshch. 26(10), 36 (2011).
M. Ristova, M. Ristov, and P. Tosev, Thin Solid Films 315, 301 (1998).
A. Yu. Chufarov, N. A. Forostyanaya, A. N. Ermakov, et al., Russ. J. Inorg. Chem. 58, 1220 (2013).
Z. I. Smirnova, L. N. Maskaeva, V. I. Voronin, and V. F. Markov, Butlerov. Soobshch. 33(2), 99 (2013).
Yu. Yu. Lur’e, Handbook on Analytical Chemistry (Khimiya, Moscow, 1971).
A. Balandin, K. L. Wang, and N. Kouklin, Appl. Phys. Lett. 76, 137 (2000).
Rajeev R. Prabhu and M. Abdul Khadar, Bull. Mater. Sci. 31, 511 (2008).
R. Sherwing, R. J. H. Clark, and R. Lauck, Solid State Commun. 134, 565 (2005).
Z. I. Smirnova, Extended Abstract of Candidate Dissertation in Chemistry (UrFU, Ekaterinburg, 2013) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.N. Maskaeva, N.A. Forostyanaya, V.F. Markov, V.I. Voronin, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 5, pp. 618–625.
Rights and permissions
About this article
Cite this article
Maskaeva, L.N., Forostyanaya, N.A., Markov, V.F. et al. Synthesis of films of solid solutions Cd x Pb1 − x S by the method of ion-exchange substitution. Russ. J. Inorg. Chem. 60, 552–559 (2015). https://doi.org/10.1134/S0036023615050150
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023615050150