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Behavior of associates of keplerate-type porous spherical Mo72Fe30 clusters with metal cations in electric field-driven ion transport

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Abstract

It has been demonstrated that the keplerate-type porous spherical Mo72Fe30 cluster is stable upon association with multicharged metal cations (calcium, lanthanum) in aqueous solutions. The behavior of Mo72Fe30 keplerate associates with lanthanum ions attests to the possibility of transfer of such associates in electric field-induced transport of cationic forms, in particular, upon electrophoretic delivery in living systems. Lanthanum ions can be used as labels for monitoring polyoxometallate transfer in different media.

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Authors and Affiliations

  1. Ural Federal University Named after the First President of Russia B.N. Yel’tsin (Research Institute of Physics and Applied Mathematics), ul. Mira 19, Yekaterinburg, 620002, Russia

    A. A. Ostroushko, I. G. Danilova, I. F. Gette & M. O. Tonkushina

  2. Institute of Immunology and Physiology, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 106, Yekaterinburg, 620219, Russia

    I. G. Danilova & M. O. Tonkushina

Authors
  1. A. A. Ostroushko
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  2. I. G. Danilova
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  3. I. F. Gette
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  4. M. O. Tonkushina
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Correspondence to A. A. Ostroushko.

Additional information

Original Russian Text © A.A. Ostroushko, I.G. Danilova, I.F. Gette, M.O. Tonkushina, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 4, pp. 561–565.

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Ostroushko, A.A., Danilova, I.G., Gette, I.F. et al. Behavior of associates of keplerate-type porous spherical Mo72Fe30 clusters with metal cations in electric field-driven ion transport. Russ. J. Inorg. Chem. 60, 500–504 (2015). https://doi.org/10.1134/S003602361504018X

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  • DOI: https://doi.org/10.1134/S003602361504018X

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