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Specifics of reaction between tri-ortho-tolylantimony and cyclohexanone oxime in the presence of peroxides: Structure of tri-ortho-tolylantimony bis(cyclohexanone oximate) and its adduct with tri-ortho-tolylantimony oxide

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Abstract

Tri-ortho-tolylantimony bis(cyclohexanone oximate) (o-Tol)3Sb(ON=C6H10-cyclo)2 (I) has been synthesized by the reaction between tri-o-tolylantimony and cyclohexanone oxime in the presence of tert-butyl hydroperoxide (1: 2: 1 mol/mol/mol). When the molar ratio of reagents was 1: 1: 1, the adduct (o-Tol)3Sb(ON=C6H10-cyclo)2 · [(o-Tol)3SbO]2 (II) has been isolated from the reaction. According to X-ray diffraction data, the axial OSbO and equatorial CSbC angles in complex I are 168.61(7)° and 112.4(1)°–124.2(1)°, respectively. The Sb-C and Sb-O bonds are 2.123(3)–2.126(2) and 2.062(2), 2.068(2) Å, respectively. The molecules in adduct II have geometric parameters close to the respective parameters of the individually crystallizing compounds.

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Authors and Affiliations

  1. National South Ural State Research University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina, E. V. Artem’eva & M. S. Makerova

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. E. V. Artem’eva
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  4. M. S. Makerova
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, E.V. Artem’eva, M.S. Makerova, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 2, pp. 207–212.

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Sharutin, V.V., Sharutina, O.K., Artem’eva, E.V. et al. Specifics of reaction between tri-ortho-tolylantimony and cyclohexanone oxime in the presence of peroxides: Structure of tri-ortho-tolylantimony bis(cyclohexanone oximate) and its adduct with tri-ortho-tolylantimony oxide. Russ. J. Inorg. Chem. 60, 170–175 (2015). https://doi.org/10.1134/S0036023615020138

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  • DOI: https://doi.org/10.1134/S0036023615020138

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