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On equilibria with participation of gold(I) complexes in sulfite-thiocarbamide media

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Abstract

The constants of protonation and sulfite ligand substitution by thiocarbamide for Au(SO3) 3−2 complex were determined. Mixed forms Autu(SO3)− and probably binuclear complex [Au2tu2SO3] were shown to occur in noticeable concentrations in sulfite-thiocarbamide media in addition to Autu +2 and Au(SO3) 3−2 complex forms.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    I. V. Mironov, D. B. Kal’nyi & V. V. Kokovkin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    I. V. Mironov

Authors
  1. I. V. Mironov
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  2. D. B. Kal’nyi
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  3. V. V. Kokovkin
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Correspondence to I. V. Mironov.

Additional information

Original Russian Text © I.V. Mironov, D.B. Kal’nyi, V.V. Kokovkin, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 11, pp. 1603–1608.

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Mironov, I.V., Kal’nyi, D.B. & Kokovkin, V.V. On equilibria with participation of gold(I) complexes in sulfite-thiocarbamide media. Russ. J. Inorg. Chem. 59, 1355–1360 (2014). https://doi.org/10.1134/S0036023614110163

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  • DOI: https://doi.org/10.1134/S0036023614110163

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