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Thermodynamic parameters of complexation reactions between nickel(II) ion and L-serine in aqueous solutions

  • Physical Chemistry of Solutions
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Abstract

A thermochemical study of coordination equilibria in the nickel(II) ions-L-serine system was carried out. The heats of reaction between solutions of an amino acid and nickel(II) nitrate at 288.15, 298.15, and 308.15 K and ionic strength of 0.25, 0.50, and 0.75 (KNO3) were measured. The heats of dilution of nickel nitrate solution in background electrolyte solutions were determined under identical conditions to make proper corrections. The results were processed with allowance for stepwise equilibria. The standard thermodynamic parameters of the complexation processes were calculated. The effect of temperature on heats of complexation reactions in the L-serine-nickel(II) ions was studied. The standard enthalpies of formation of NiSer+, NiSer2, and NiSer 3 complexes in aqueous solutions were determined.

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Correspondence to L. A. Kochergina.

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Original Russian Text © L.A. Kochergina, O.M. Drobilova, S.E. Sivkina, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 11, pp. 1594–1602.

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Kochergina, L.A., Drobilova, O.M. & Sivkina, S.E. Thermodynamic parameters of complexation reactions between nickel(II) ion and L-serine in aqueous solutions. Russ. J. Inorg. Chem. 59, 1346–1354 (2014). https://doi.org/10.1134/S0036023614110096

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  • DOI: https://doi.org/10.1134/S0036023614110096

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