Abstract
Copper(II) coordination compounds with 3-(pyridin-2-yl)-5-(2-salicylideniminophenyl)-1H-1,2,4-triazole and 1,3-bis(5-(pyridin-2-yl)-1,2,4-triazole-3-yl)propane have been synthesized. The complexes have been studied by elemental and thermal analysis, IR and electron spectroscopy, electron paramagnetic resonance (EPR), and magnetochemistry. According to X-ray diffraction data, the complexes have binuclear structures in which metal cations are bonded via the nitrogen atoms of two bridging triazole rings.
Similar content being viewed by others
References
R. L. Carlin, Magnetochemistry (Springer, London, 2011).
V. T. Kalinnikov, Yu. V. Rakitin, and V. M. Novotortsev, Russ. Chem. Rev. 72, 995 (2003).
R. M. Roat-Malone, Bioinorganic Chemistry: A Short Course (Wiley-Interscience, New Jersey, 2002).
D. Desbouis, I. P. Troitsky, M. J. Belousoff, et al., Coord. Chem. Rev. 256, 897 (2012).
S. R. Pauleta, S. Dell’Acqua, and I. Moura, Coord. Chem. Rev. 257, 332 (2013).
D. J. Chesnut, A. Kusnetzow, R. Birge, et al., Inorg. Chem. 38, 5484 (1999).
A. B. Lysenko, E. V. Govor, H. Krautscheid, et al., Dalton Trans., No. 31, 3772 (2006).
W. Ouellette, J. R. Galan-Mascaros, K. R. Dunbar, et al., Inorg. Chem. 45, 1909 (2006).
W. Ouellette, A. V. Prosvirin, V. Chieffo, et al., Inorg. Chem. 45, 9346 (2006).
M. H. Klingele and S. Brooker, Coord. Chem. Rev. 241, 119 (2003).
G. Aromi, L. A. Barrios, O. Roubeau, et al., Coord. Chem. Rev. 255, 485 (2011).
P. M. Slangen, P. J. van Koningsbruggen, J. G. Haasnoot, et al., Inorg. Chim. Acta 212, 289 (1993).
S. Ferrer, P. J. van Koningsbruggen, J. G. Haasnoot, et al., J. Chem. Soc., Dalton Trans., No. 23, 4269 (1999).
A. N. Gusev, M. Hasegawa, G. A. Nishchymenko, et al., J. Chem. Soc., Dalton Trans. 42, 6936 (2013).
A. N. Gusev, V. F. Shul’gin, O. V. Konnic, et al., Inorg. Chim. Acta 376, 509 (2011).
Yu. V. Rakitin and V. T. Kalinnikov, Advanced Magnetochemistry (Nauka, St. Petersburg, 1994) [in Russian].
SMART (control) and SAINT (integration) Sofware. Version 5.0 (Bruker, Madison (WI, USA), 1997).
G. M. Sheldrick, SHELXL-97. Program for the Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).
A. Levér, Inorganic Electronic Spectroscopy (Elsevier, Amsterdam, 1984), Vol. 2.
A. W. Addison, T. N. Rao, J. Reedijk, et al., J. Chem. Soc., Dalton Trans., No. 7, 1349 (1984).
P. M. Slangen, P. J. van Koningsbruggen, K. Goubitz, et al., Inorg. Chem. 33, 1121 (1994).
R. Prins, R. A. G. de Graaff, J. G. Haasnoot, et al., J. Chem. Soc., Chem. Commun., No. 18, 1430 (1986).
Yu. V. Rakitin, G. M. Larin, and V. V. Minin, Interpretation of EPR Spectra of Cooridnation Compounds (Nauka, Moscow, 1993) [in Russian].
Ya. S. Lebedev and V. I. Muromtsev, EPR and the Relaxation of Stabilized Radicals (Khimiya, Moscow, 1972) [in Russian].
R. Wilson and D. Kivelson, J. Chem. Phys. 44, 154 (1966).
Yu. V. Rakitin, V. V. Volkov, and V. T. Kalinnikov, Koord. Khim. 7, 1622 (1981).
V. A. Kogan and V. V. Lukov, Koord. Khim. 19, 476 (1993).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.N. Gusev, V.F. Shul’gin, E.A. Ugolkova, N.N. Efimov, G.G. Aleksandrov, V.V. Minin, I.L. Eremenko, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 7, pp. 910–916.
Rights and permissions
About this article
Cite this article
Gusev, A.N., Shul’gin, V.F., Ugolkova, E.A. et al. Binuclear copper(II) complexes of functionalized 1,2,4-triazoles: Synthesis, structure, and magnetic properties. Russ. J. Inorg. Chem. 59, 699–705 (2014). https://doi.org/10.1134/S0036023614070055
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023614070055