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Binuclear copper(II) complexes of functionalized 1,2,4-triazoles: Synthesis, structure, and magnetic properties

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Abstract

Copper(II) coordination compounds with 3-(pyridin-2-yl)-5-(2-salicylideniminophenyl)-1H-1,2,4-triazole and 1,3-bis(5-(pyridin-2-yl)-1,2,4-triazole-3-yl)propane have been synthesized. The complexes have been studied by elemental and thermal analysis, IR and electron spectroscopy, electron paramagnetic resonance (EPR), and magnetochemistry. According to X-ray diffraction data, the complexes have binuclear structures in which metal cations are bonded via the nitrogen atoms of two bridging triazole rings.

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Correspondence to A. N. Gusev.

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Original Russian Text © A.N. Gusev, V.F. Shul’gin, E.A. Ugolkova, N.N. Efimov, G.G. Aleksandrov, V.V. Minin, I.L. Eremenko, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 7, pp. 910–916.

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Gusev, A.N., Shul’gin, V.F., Ugolkova, E.A. et al. Binuclear copper(II) complexes of functionalized 1,2,4-triazoles: Synthesis, structure, and magnetic properties. Russ. J. Inorg. Chem. 59, 699–705 (2014). https://doi.org/10.1134/S0036023614070055

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  • DOI: https://doi.org/10.1134/S0036023614070055

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