Skip to main content
SpringerLink
Log in

Ternary telluride phases crystallizing in the polythermal non-quasi-binary section Cu2Cr4Te7-Te in the quasi-ternary system Cu2Te-Cr2Te3-Te

  • Physicochemical Analysis of Inorganic Systems
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The interaction in the section Cu2Cr4Te7-Te of the quasi-ternary system Cu2Te-Cr2Te3-Te was studied by physicochemical analysis methods (differential thermal, X-ray powder diffraction, and microstructural analyses) and also by analyzing the temperature dependences of the specific magnetization of samples. In the section, there is a wide region of homogeneity of solid solutions based on Cu2Cr4Te7, which extends at room temperature to 42 at %, and there are also regions of crystallization of two more ternary tellurides, Cu4Cr8Te17 and CuCr2Te5. The characteristics of the formation and melting of the obtained phases were found. The Curie temperatures of the solid solutions based on Cu2Cr4Te7 are 285–325 K, and those of Cu4Cr8Te17 and CuCr2Te5 are 270 and 190 K, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. I. Yarembash and A. A. Eliseev, Rare-Earth Metal Chalcogenides (Nauka, Moscow, 1975) [in Russian].

    Google Scholar 

  2. N. P. Luzhnaya, G. G. Shabunina, T. G. Aminov, and V. T. Kalinnikov, Zh. Neorg. Khim. 26, 1075 (1982).

    Google Scholar 

  3. V. Ya. Anosov and S. A. Pogodin, Fundamentals of Physicochemical Analysis (Akad. Nauk SSSR, Moscow, 1947) [in Russian].

    Google Scholar 

  4. H. Hahn and C. de Lorent, Z. Anorg. Allg. Chem. 290(1–2), 68 (1957).

    Article  CAS  Google Scholar 

  5. F. K. Lotgering and C. H. van der Steen, Solid State Commun. 9, 1741 (1971).

    Article  CAS  Google Scholar 

  6. A. A. Babitsyna and T. A. Emel’yanova, Zh. Neorg. Khim. 40(10), 2730 (1995).

    Google Scholar 

  7. A. A. Babitsyna, T. A. Emel’yanova, L. I. Koroleva, and A. I. Kuz’minykh, Izv. Akad. Nauk SSSR, Neorg. Mater. 22, 1743 (1986).

    CAS  Google Scholar 

  8. A. A. Babitsyna, T. A. Emel’yanova, and T. I. Koneshova, Russ. J. Inorg. Chem. 45, 1276 (2000).

    Google Scholar 

  9. A. V. Filatov, Candidate’s Dissertation in Chemistry (Inst. Obshch. Neorh. Khim. Akad. Nauk SSSR, Moscow, 1980).

  10. H. Ipser and H. L. Komarek, J. Less-Common Met. 93, 265 (1983).

    Article  Google Scholar 

  11. T. I. Koneshova, A. A. Babitsyna, and T. A. Emel’yanova, Russ. J. Inorg. Chem. 46, 1736 (2001).

    Google Scholar 

  12. A. Yu. Vol’fkovich, Candidate’s Dissertation in Chemistry (Inst. Obshch. Neorh. Khim. Ross. Akad. Nauk, Moscow, 1999).

  13. Inorganic Chromium Compounds: Handbook. V. A. Ryabin, M. V. Kireeva, N. A. Berg, et al., (Khimiya, Leningrad, 1981), p. 208 [in Russian].

    Google Scholar 

  14. T. Ohachi and B. R. Pamplin, J. Cryst. Growth 42, 598 (1977).

    Article  CAS  Google Scholar 

  15. D. M. Gambarov, G. G. Guseinov, and Z. Sh. Karaev, Izv. Akad. Nauk SSSR, Neorg. Mater. 8(12), 2211 (1972).

    Google Scholar 

  16. A. Congin, L. Garbato, and S. Serci, Phys. Status Solidi A 5, 515 (1971).

    Google Scholar 

  17. T. N. Koneshova and V. T. Kalinnikov, Izv. Akad. Nauk SSSR, Neorg. Mater. 21, 386 (1985).

    CAS  Google Scholar 

  18. T. I. Koneshova, Izv. Akad. Nauk SSSR, Neorg. Mater. 26(9), 1990 (1990).

    Google Scholar 

  19. T. I. Koneshova, A. A. Babitsyna, and V. T. Kalinnikov, Elektron. Tekh., Ser. 6: Mater., No. 6(235), 25 (1988).

    Google Scholar 

  20. T. I. Koneshova, Neorg. Mater. 29, 47 (1993).

    Google Scholar 

  21. Yu. V. Rakitin and V. T. Kalinnikov, Modern Magnetochemistry (Nauka, St. Petersburg, 1994) [in Russian).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Mendeleev Russian University of Chemical Engineering, Moscow, Russia

    T. I. Koneshova & N. I. Kudryashov

Authors
  1. T. I. Koneshova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. I. Kudryashov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. I. Kudryashov.

Additional information

Original Russian Text © T.I. Koneshova, N.I. Kudryashov, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 6, pp. 789–793.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Koneshova, T.I., Kudryashov, N.I. Ternary telluride phases crystallizing in the polythermal non-quasi-binary section Cu2Cr4Te7-Te in the quasi-ternary system Cu2Te-Cr2Te3-Te. Russ. J. Inorg. Chem. 59, 609–613 (2014). https://doi.org/10.1134/S0036023614060102

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023614060102

Keywords

Search

Navigation