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Synthesis and structure of N-(hydroxyethyl)ethylenediammonium sulfite monohydrate

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Abstract

A reaction between sulfur(IV) oxide and aqueous N-(2-hydroxyethyl)ethylenediamine yields onium sulfite of composition (HOCH2CH2NH2CH2CH2NH3)SO3 · H2O, which has been characterized by X-ray diffraction, IR spectroscopy, and mass spectrometry. The three-dimensional structure of the salt is stabilized by numerous hydrogen bonds, such as NH…O and OH…O.

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Authors and Affiliations

  1. Physicochemical Institute for Human and Environment Protection, Ministry of Education and Science of Ukraine, National Academy of Sciences of Ukraine, ul. Preobrazhenskaya 3, Odessa, 65026, Ukraine

    R. E. Khoma & A. A. Ennan

  2. Mechnikov National University, ul. Dvoryanskaya 2, Odessa, 65025, Ukraine

    R. E. Khoma

  3. Odessa National Medical University, per. Valikhovskiy 2, Odessa, 65026, Ukraine

    V. O. Gelmboldt

  4. Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, Kharkiv, 61178, Ukraine

    O. V. Shishkin, V. N. Baumer & A. N. Puzan

  5. Kharkiv National University, pl. Svobody 4, Kharkiv, 61077, Ukraine

    O. V. Shishkin & V. N. Baumer

  6. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfskaya doroga 86, Odessa, 65080, Ukraine

    I. M. Rakipov

Authors
  1. R. E. Khoma
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  2. V. O. Gelmboldt
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  3. O. V. Shishkin
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  4. V. N. Baumer
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  5. A. N. Puzan
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  6. A. A. Ennan
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  7. I. M. Rakipov
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Corresponding author

Correspondence to R. E. Khoma.

Additional information

Original Russian Text © R.E. Khoma, V.O. Gelmboldt, O.V. Shishkin, V.N. Baumer, A.N. Puzan, A.A. Ennan, I.M. Rakipov, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 6, pp. 716–719.

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Khoma, R.E., Gelmboldt, V.O., Shishkin, O.V. et al. Synthesis and structure of N-(hydroxyethyl)ethylenediammonium sulfite monohydrate. Russ. J. Inorg. Chem. 59, 541–544 (2014). https://doi.org/10.1134/S0036023614060096

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  • DOI: https://doi.org/10.1134/S0036023614060096

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