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Phase equilibria in MF2-YbF3-ScF3 (M = Cd or Mg) systems and isomorphic substitutions stabilizing α-YF3 type structures

  • Physicochemical Analysis of Inorganic Systems
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Abstract

Phase equilibria in MF2-YbF3-ScF3 (M = Cd, Mg) systems were studied by differential thermal analysis. The systems are of eutectic type without intermediate phases. CdF2-, α-YbF3-, and β-YbF3-based solid solutions only exist. The low-temperature stability boundary of α-YbF3-based solid solution is 833 ± 5°C in the cadmium-containing system and 852°C in the magnesium-containing system.

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Authors and Affiliations

  1. Prokhorov Institute for General Physics, Russian Academy of Sciences, Leninskii pr. 51, Moscow, 119991, Russia

    P. P. Fedorov

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  1. P. P. Fedorov
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Correspondence to P. P. Fedorov.

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Original Russian Text © P.P. Fedorov, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 6, pp. 775–779.

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Fedorov, P.P. Phase equilibria in MF2-YbF3-ScF3 (M = Cd or Mg) systems and isomorphic substitutions stabilizing α-YF3 type structures. Russ. J. Inorg. Chem. 59, 595–599 (2014). https://doi.org/10.1134/S0036023614060072

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  • DOI: https://doi.org/10.1134/S0036023614060072

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