Russian Journal of Inorganic Chemistry

, Volume 59, Issue 5, pp 431–440 | Cite as

Electrochemical and chemical synthesis and structure of adducts (CH3OH and H2O) of metal chelates of N,N,O tridentate pyrazole-containing Schiff base

  • D. A. Garnovskii
  • A. S. Antsyshkina
  • A. V. Churakov
  • G. G. Sadikov
  • V. S. Sergienko
  • I. S. Vasil’chenko
  • A. I. Uraev
  • V. G. Vlasenko
  • Ya. V. Zubavichus
  • S. I. Levchenkov
  • Yu. V. Revinskii
  • A. S. Burlov
Coordination Compounds

Abstract

Chemical and electrochemical synthesis of a series of cobalt(II), nickel(II), copper(II), and zinc(II) complexes of tridentate Schiff base (H2L), a product of condensation of N-(2-aminophenyl)-4-methylbenzenesulfonamide (2-tosylaminoaniline) with 1-phenyl-3-methyl-4-formylpyrazol-5-ol was accomplished. The structure and composition of metal-chelates were established by the C, H, N elemental analysis, IR, 1H NMR, EXAFS spectroscopy and magnetochemical data. The structures of all complexes were confirmed by of X-ray crystallography.

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References

  1. 1.
    A. I. Uraev, I. S. Vasilchenko, V. N. Ikorskii, et al., Mendeleev Commun. 15, 133 (2005).CrossRefGoogle Scholar
  2. 2.
    M. Bernal, J. A. García-Vazquez, J. Romero, et al., Inorg. Chim. Acta 295, 39 (1999).CrossRefGoogle Scholar
  3. 3.
    A. D. Garnovskii, A. S. Burlov, D. A. Garnovskii, et al., Polyhedron 18, 1985 (1999).CrossRefGoogle Scholar
  4. 4.
    J. Sanmartín, F. Novio, A. M. García-Deibe, et al., Eur. J. Inorg. Chem., No. 10, 1719 (2008).Google Scholar
  5. 5.
    D. A. Garnovskii, M. F. C. Guedes Da Silva, M. N. Kopylovich, et al., Polyhedron 22, 1335 (2003).CrossRefGoogle Scholar
  6. 6.
    A. Sousa-Pedrares, J. A. Viqueira, J. Antelo, et al., Eur. J. Inorg. Chem., No. 17, 2273 (2011).Google Scholar
  7. 7.
    B. A. Porai-Koshits and I. Ya. Kvitko, Zh. Obshch. Khim. 34, 2999 (1964).Google Scholar
  8. 8.
    W. U. Malick and T. S. Sharma, J. Ind. Chem. Soc. 47, 167 (1970).Google Scholar
  9. 9.
    D. G. Tuck, Pure Appl. Chem. 51, 2005 (1979).CrossRefGoogle Scholar
  10. 10.
    A. A. Chernyshov, A. A. Veligzhanin, and Y. V. Zubavichus, Nucl. Instr. Meth. Phys. Res. A 603, 95 (2009).CrossRefGoogle Scholar
  11. 11.
    M. Newville, J. Synchrotron Radiat., No. 8, 96 (2001).Google Scholar
  12. 12.
    S. I. Zabinski, J. J. Rehr, A. Ankudinov, et al., Phys. Rev. B 52, 2995 (1995).CrossRefGoogle Scholar
  13. 13.
    SMART (Control) and SAINT (Integration) Software, Version 5.0, Bruker AXS Inc., Madison (1997).Google Scholar
  14. 14.
    G. M. Sheldrick, Program for the Solution of Crystal Structure. Göttingen, Germany (1986).Google Scholar
  15. 15.
    G. M. Sheldrick, Program for the Refinement of Crystal Structure. Göttingen, Germany (1997).Google Scholar
  16. 16.
    A. S. Antsyshkina, G. G. Sadikov, A. I. Uraev, et al., Kristallografiya 45, 850 (2000).Google Scholar
  17. 17.
    R. N. Jadeja, J. R. Snan, E. Suresh, and P. Parimal, Polyhedron 23, 2465 (2004).CrossRefGoogle Scholar
  18. 18.
    G.-C. Xu, L. Zhang, L. Liu, et al., Polyhedron 27, 12 (2008).CrossRefGoogle Scholar
  19. 19.
    J. S. Casas and M. S. García-Tasende, A. Sánchez, et al., Coord. Chem. Rev. 251, 1561 (2007).CrossRefGoogle Scholar
  20. 20.
    S. A. Levchenkov, I. N. Shcherbakov, L. D. Popov, et al., Inorg. Chim. Acta 405, 169 (2013).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • D. A. Garnovskii
    • 1
    • 3
  • A. S. Antsyshkina
    • 2
  • A. V. Churakov
    • 2
  • G. G. Sadikov
    • 2
  • V. S. Sergienko
    • 2
  • I. S. Vasil’chenko
    • 3
  • A. I. Uraev
    • 3
  • V. G. Vlasenko
    • 4
  • Ya. V. Zubavichus
    • 5
  • S. I. Levchenkov
    • 1
  • Yu. V. Revinskii
    • 1
  • A. S. Burlov
    • 3
  1. 1.South Research CenterRussian Academy of SciencesRostov-na-DonuRussia
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia
  3. 3.Research Institute of Physical and Organic ChemistrySouthern Federal UniversityRostov-na-DonuRussia
  4. 4.Research Institute of PhysicsSouthern Federal UniversityRostov-na-DonuRussia
  5. 5.Russian Research Center “Kurchatov Institute”MoscowRussia

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