Electrochemical and chemical synthesis and structure of adducts (CH3OH and H2O) of metal chelates of N,N,O tridentate pyrazole-containing Schiff base
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- Garnovskii, D.A., Antsyshkina, A.S., Churakov, A.V. et al. Russ. J. Inorg. Chem. (2014) 59: 431. doi:10.1134/S0036023614050088
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Chemical and electrochemical synthesis of a series of cobalt(II), nickel(II), copper(II), and zinc(II) complexes of tridentate Schiff base (H2L), a product of condensation of N-(2-aminophenyl)-4-methylbenzenesulfonamide (2-tosylaminoaniline) with 1-phenyl-3-methyl-4-formylpyrazol-5-ol was accomplished. The structure and composition of metal-chelates were established by the C, H, N elemental analysis, IR, 1H NMR, EXAFS spectroscopy and magnetochemical data. The structures of all complexes were confirmed by of X-ray crystallography.