Abstract
The thermal decomposition of CsAlH4 was found to involve the formation of a previously unknown intermediate CsAl3H8 as probed by DTA, IR, and NMR spectroscopy.
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E. H. Majzoub, E. Hazrati, and G. A. de Wijs, J. Phys. Chem. 117, 8864 (2013).
E. G. S. Sorte, R. C. Jr. Bowman, E. H. Majzoub, et al., Phys. Chem., 117, 8105 (2013).
V. P. Tarasov, S. I. Bakum, and A. V. Novikov, Russ. J. Inorg. Chem. 48, 722 (2003).
P. Vajeeston, P. Ravindran, R. Vidya, et al., Cryst. Growth Des. 4, 471 (2004).
C. Weidenthaler, T. J. Frankcombe, and M. Felderhoff, J. Chem. 45, 3849 (2006).
A. V. Novikov, Candidate Dissertation in Chemistry (Kurnakov Inst. of Gen. and Inorg. Chem., Moscow, 2003).
S. I. Bakum and S. F. Ereshko, Izv. Akad. Nauk SSSR, Ser. Khim., No. 10, 2183 (1981).
T. G. Adiks, V. V. Gavrilenko, L. I. Zakharkin, and L. A. Ignat’eva, Zh. Prikl. Spectrosk. 6, 806 (1967).
A. S. Zyubin, Russ. J. Inorg. Chem. 42, 600 (1997).
L. Lavine and W. N. Lipscomb, J. Chem. Phys. 21, 2087 (1953).
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Original Russian Text © S.I. Bakum, S.F. Kuznetsova, V.P. Tarasov, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 12, pp. 1657–1659.
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Bakum, S.I., Kuznetsova, S.F. & Tarasov, V.P. CsAlH4 thermolysis. Russ. J. Inorg. Chem. 58, 1547–1549 (2013). https://doi.org/10.1134/S0036023613120048
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DOI: https://doi.org/10.1134/S0036023613120048