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Synthesis, crystal, and molecular structure of the solvated complex [MoO2(L)] · DMF (L2− = 2-[N-(2-hydroxynaphthylidene)amino]propane-1,2,3-triol anion)

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Abstract

A new dioxomolybdenum(VI) complex, [MoO2(L)] · DMF, where L2− = 2-[N-(2-hydroxynaphthylidene)amino]propane-1,2,3-triol, has been synthesized. Its structure has been determined by X-ray diffraction analysis. The Mo atom is octahedrally coordinated by two oxo ligands that are in cis-positions with respect to each other, two oxygen atoms, the nitrogen atom of the tridentate bis(chelate) ligand L, and the DMF oxygen atom.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. S. Sergienko & V. I. Sokol

  2. Dal’ East Ukrainian National University, Molodezhnyi kvartal 20a, Lugansk, 91034, Ukraine

    V. L. Abramenko

Authors
  1. V. S. Sergienko
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  2. V. L. Abramenko
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  3. V. I. Sokol
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Original Russian Text © V.S. Sergienko, V.L. Abramenko, V.I. Sokol, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 9, pp. 1172–1176.

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Sergienko, V.S., Abramenko, V.L. & Sokol, V.I. Synthesis, crystal, and molecular structure of the solvated complex [MoO2(L)] · DMF (L2− = 2-[N-(2-hydroxynaphthylidene)amino]propane-1,2,3-triol anion). Russ. J. Inorg. Chem. 58, 1047–1051 (2013). https://doi.org/10.1134/S0036023613090209

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  • DOI: https://doi.org/10.1134/S0036023613090209

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