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Aluminum, gallium, and indium oxopivalates: Thermodynamic characteristics of gallium oxopivalates

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Abstract

Aluminum, gallium, and indium oxopivalates were synthesized by a heterophase method, and their evaporation was studied by the Knudsen effusion method with the mass-spectral analysis of the gas phase. It was shown that oxopivalates can be considered within binary systems as compounds of the type mM(piv)3 · nM2O3. The standard enthalpies of formation of gallium oxopivalates Ga3O(piv)7(gas), 7Ga(piv)3 · Ga2O3(solid), 4Ga(piv)3 · Ga2O3(solid), and 7Ga(piv)3 · 2Ga2O3(solid) were found.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    D. B. Kayumova, N. G. Yaryshev & A. V. Steblevskii

  2. Moscow Pedagogical State University, Malaya Pirogovskaya ul. 1, Moscow, 119882, Russia

    N. N. Kamkin, I. A. Dement’ev & A. S. Alikhanyan

Authors
  1. D. B. Kayumova
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  2. N. N. Kamkin
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  3. N. G. Yaryshev
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  4. A. V. Steblevskii
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  5. I. A. Dement’ev
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  6. A. S. Alikhanyan
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Additional information

Original Russian Text © D.B. Kayumova, N.N. Kamkin, N.G. Yaryshev, A.V. Steblevskii, I.A. Dement’ev, A.S. Alikhanyan, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 7, pp. 946–949.

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Kayumova, D.B., Kamkin, N.N., Yaryshev, N.G. et al. Aluminum, gallium, and indium oxopivalates: Thermodynamic characteristics of gallium oxopivalates. Russ. J. Inorg. Chem. 58, 839–842 (2013). https://doi.org/10.1134/S0036023613070139

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  • DOI: https://doi.org/10.1134/S0036023613070139

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