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Chemical and thermal destruction of the platinum blue {Pt(Bipy)(NHCOCH3)2NO3 · mH2O}. The molecular and crystal structures of new binuclear Pt(III) acetamide [Pt2(Bipy)2(NHCOCH3)2(μ-NHCOCH3)2](NO3)2 · H2O

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Abstract

The chemical reactivity of mixed-valence “platinum blue” of the composition [Pt(Bipy)(NHCOCH3)2NO3 · mH2O] n (I) towards water, concentrated HCl, and ethanol was studied. The reaction of compound I with water gave previously unknown binuclear Pt(III) acetamide [Pt2(Bipy)2(μ-NHCOCH3)2(NHCOCH3)2](NO3)2 · H2O (II) (yield 19%), which was studied by X-ray diffraction. Upon the reaction of “blue” I with HClconc, destruction took place to give PtBipyCl3 and Pt(IV) oxonium hexachloroplatinate (H3O)2[PtCl6] the structure of which was studied by X-ray diffraction; treatment of I with ethanol leads to partial reduction of the “blue” and destruction giving (according to X-ray diffraction data) the Pt(II) complex [Pt(Bipy)2](NO3)2 · H2O (III). Thermal decomposition of I under inert atmosphere was studied by DSC and TGA.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    T. N. Fedotova, G. G. Aleksandrov, Zh. V. Dobrokhotova, G. N. Kuznetsova & I. L. Eremenko

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  1. T. N. Fedotova
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  2. G. G. Aleksandrov
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  3. Zh. V. Dobrokhotova
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  4. G. N. Kuznetsova
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  5. I. L. Eremenko
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Original Russian Text © T.N. Fedotova, G.G. Aleksandrov, Zh.V. Dobrokhotova, G.N. Kuznetsova, I.L. Eremenko, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 7, pp. 879–885.

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Fedotova, T.N., Aleksandrov, G.G., Dobrokhotova, Z.V. et al. Chemical and thermal destruction of the platinum blue {Pt(Bipy)(NHCOCH3)2NO3 · mH2O}. The molecular and crystal structures of new binuclear Pt(III) acetamide [Pt2(Bipy)2(NHCOCH3)2(μ-NHCOCH3)2](NO3)2 · H2O. Russ. J. Inorg. Chem. 58, 777–782 (2013). https://doi.org/10.1134/S0036023613070073

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  • DOI: https://doi.org/10.1134/S0036023613070073

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