Abstract
It was shown that, in the systems Sr-Co-M-O (M=Zn, Cu), the first stage of the crystallization of solid solutions Sr3Co2 − x M x O6 with a tetragonal structure of the Ruddlesden-Popper type is the formation of quasi-one-dimensional oxides of the family A3m+3n A n ′B3m+n O9m+6n . The magnetic properties of new compounds, Sr3Co1.35Cu0.65O6 and Sr14Co8.4Cu2.6O33, were measured, and a relationship between the structure and the existence of magnetic ordering at low temperatures was established.
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References
F. Abraham, S. Minaud, and C. Renard, J. Mater. Chem. 4(11), 1763 (1994).
A. E. Abed, E. Gaudin, S. Lemaux, and J. Darriet, J. Solid State Sci., No. 3, 887 (2001).
K. Mori, T. Kamiyama, H. Kobayashi, et al., Appl. Phys. A 74, 914 (2002).
Y. Breard, C. Michel, A. Maignan, and B. Raveau, Solid State Commun. 118, 517 (2001).
S. E. Dann and M. T. Weller, J. Solid State Chem. 115, 499 (1995).
L. Mogni, F. Prado, H. Ascolani, et al., J. Solid State Chem. 178, 1559 (2005).
S. E. Dann, M. T. Weller, and V. Currie, J. Solid State Chem. 97, 179 (1992).
T. I. Chupakhina, N. A. Zaitseva, M. A. Melkozerova, and G. V. Bazuev, Russ. J. Inorg. Chem. 51, 1157 (2006).
I. A. Zvereva, V. F. Popova, N. S. Pylkina, and V. V. Gusarov, Russ. J. Gen. Chem. 73, 43 (2003).
T. I. Chupakhina, G. V. Bazuev, and E. V. Zabolotskaya, Russ. J. Inorg. Chem. 55, 247 (2010).
T. I. Chupakhina, G. V. Bazuev, and N. A. Zaitseva, Russ. J. Inorg. Chem. 49, 661 (2004).
W. Harrison, S. Hegwood, and A. Jacobson, J. Chem. Soc., Chem. Commun., 1953 (1995).
O. Gourdon, V. Petricek, M. Dusek, et al., Acta Crystallogr. B55, 841 (1999).
K. Boulahya, M. Parras, J. M. Gonzalez-Calbet, and J. L. Martinez, Chem. Mater. 15, 3537 (2003).
S. Van Smaalen, Crystallogr. Rev. 4, 179 (1995).
M. A. Melkozerova and G. V. Bazuev, Russ. J. Inorg. Chem. 51, 362 (2006).
M. A. Melkozerova, T. I. Chupakhina, and G. V. Bazuev, in Proceedings of the Tenth International Symposium on the Order, Disorder, and Properties of Oxides, Rostov-on-Don, 2007, part II, p. 164 [in Russian].
R. D. Shannon, Acta Crystallogr. Sect. A32, 751 (1976).
Y. Breard, C. Michel, A. Maignan, and B. Raveau, Solid State Commun. 118(10), 517 (2001).
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Original Russian Text © T.I. Chupakhina, M.A. Melkozerova, G.V. Bazuev, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 3, pp. 299–305.
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Chupakhina, T.I., Melkozerova, M.A. & Bazuev, G.V. Phase formation features and magnetic properties of complex oxides in the systems Sr-Co-M-O (M = Zn, Cu). Russ. J. Inorg. Chem. 58, 253–258 (2013). https://doi.org/10.1134/S0036023613030054
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DOI: https://doi.org/10.1134/S0036023613030054