Synthesis of a magnetoactive compound based on iron(II) sulfate

Russian Journal of Inorganic Chemistry volume 58, pages14–18(2013)Cite this article

Abstract

The effect of synthesis parameters on properties of a magnetoactive compound (MAC) prepared via condensation of iron(II) sulfate in the presence of sodium nitrite is investigated. It is found that nitrite ions almost completely coprecipitate with the solid phase during the formation of a magnetoactive compound and subsequently participate in the redox conversions to yield magnetite. In order to obtain a magnetoactive compound with high relative magnetic susceptibility, condensation from the initial solutions is to be carried out at least 15 min after it is prepared; sodium nitrite consumption is to be at least 0.12 mol/mol FeSO4.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

US$ 39.95

Tax calculation will be finalised during checkout.

References

  1. 1.

    W. C. Elmore, Phys. Rew. 54, 309 (1938).

    Article  CAS  Google Scholar 

  2. 2.

    E. G. Bibik, N. S. Lavrov, N. M. Gribanov, et al., USSR Inventor’s Certificate No. 568598.

  3. 3.

    E. G. Bibik, N. M. Gribanov, O. V. Buzunov, and V. G. Germashev, USSR Inventor’s Certificate No. 861321.

  4. 4.

    E. G. Bibik, O. V. Buzunov, N. M. Gribanov, and V. G. Germashev, USSR Inventor’s Certificate No. 966015.

  5. 5.

    A. F. Tsyb, I. S. Amosov, E. E. Bibik, et al., USSR Inventor’s Certificate No. 978860.

  6. 6.

    V. G. Belikov, A. G. Kuregyan, Sh. O. Shakhshaev, and I. N. Zilfikarov, RU Patent No. 2230705.

  7. 7.

    I. Nedkov, T. Merodiiska, S. Kolev, et al., Monatsh. Chem. 133, 823 (2002).

    Article  CAS  Google Scholar 

  8. 8.

    Yu. Yu. Lur’e and A.I. Rybnikova, Chemical Analysis of Industrial Sewage (Khimiya, Moscow, 1974).

    Google Scholar 

  9. 9.

    Yu. G. Khabarov, G. V. Komarova, and E. A. Mash’yanova, Lesnoi Zh., No. 5, 124 (1988).

  10. 10.

    J. Chen, Y. G. Wang, Z. Q. Li, et al., J. Phys.: Conf. Ser. 152(1), 012041 (2009).

    Article  Google Scholar 

Download references

Author information

Affiliations

  1. Northern (Arctic) Federal University, nab. Severnoi Dviny 17, Arkhangelsk, 163002, Russia

    Yu. G. Khabarov, I. M. Babkin, L. V. Gusakov & A. V. Malkov

Authors
  1. Yu. G. Khabarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. M. Babkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. V. Gusakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Malkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. G. Khabarov.

Additional information

Original Russian Text © Yu.G. Khabarov, I.M. Babkin, L.V. Gusakov, A.V. Malkov, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 1, pp. 17–21.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Khabarov, Y.G., Babkin, I.M., Gusakov, L.V. et al. Synthesis of a magnetoactive compound based on iron(II) sulfate. Russ. J. Inorg. Chem. 58, 14–18 (2013). https://doi.org/10.1134/S0036023613010099

Download citation

Keywords

  • Nitrite
  • Magnetite
  • Sodium Nitrite
  • Magnetic Activity
  • Sulfate Heptahy Drate