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Synthesis, crystal structure and electrochemical property of 2D lamellar supermolecular complex [Cu(C6H4NO2)2 · H2O]

  • Physical Methods of Investigation
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Abstract

A 2D lamellar supermolecular complex [Cu(C6H4NO2)2 · H2O] was synthesized and characterized by elementary analysis, infrared spectrum, ultraviolet spectrum, thermogravimetry analysis and crystal X-ray diffraction analysis. The complex belongs to the orthorhombic system, Pbca space group, with a = 1.2797(8), b = 1.2944(8), c = 1.4962(9) nm, Z = 8, V = 2.478(3) nm3, D c = 1.746 g cm−3, μ = 1.784 mm−1, F(000) = 1320, R 1 = 0.0267, wR 2 = 0.0762, GOOF = 1.015, which consists of a Cu(II) ion, two 2-Picolinic acid and a coordinated water molecule. The 5-coordinated geometry of the Cu cation is a distorted tetragonal-pyramidal configuration. The 1D chain structure is formed through hydrogen bonds O(w)-H…O between single cells, and the 2D lamellar supermolecular system is formed through the non-classical hydrogen bonds C-H…O between various chains. The complex displays a distinct absorption band (λmax = 648 nm) in aqueous solution. The electrochemical behavior shows a quasi-reversible course. (CCDC: 750880)

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Authors and Affiliations

  1. College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang, Henan, 473061, China

    Yingchen Guo, Shuyang Chen, Xiaoyu Bao, Dongfang Qiu & Yuquan Feng

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  1. Yingchen Guo
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  2. Shuyang Chen
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  3. Xiaoyu Bao
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  4. Dongfang Qiu
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  5. Yuquan Feng
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Correspondence to Yingchen Guo.

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Guo, Y., Chen, S., Bao, X. et al. Synthesis, crystal structure and electrochemical property of 2D lamellar supermolecular complex [Cu(C6H4NO2)2 · H2O]. Russ. J. Inorg. Chem. 57, 1001–1004 (2012). https://doi.org/10.1134/S0036023612070121

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  • DOI: https://doi.org/10.1134/S0036023612070121

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