Skip to main content
SpringerLink
Log in

Berthollide formation conditions

  • Theoretical Inorganic Chemistry
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Possible routes to generate berthollide phases are considered, specifically, via the separation of part of a component-based solid solution due to morphotropic transitions and as a result of the intersection of the binodal line with the solidus curve. Particular example phase diagrams are given for binary systems containing berthollides. Experimental data on berthollide phase formation in systems of MF2-RF3 and NaF-RF3 (where R stands for rare-earth elements) are summed up.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. S. Kurnakov, Selected Works (Nauka, Moscow, 1960), Vol. 1 [in Russian].

    Google Scholar 

  2. P. P. Fedorov, P. I. Fedorov, and B. P. Sobolev, Zh. Neorg. Khim. 18, 3319 (1973).

    CAS  Google Scholar 

  3. P. P. Fedorov, Proceedings of the 24th Student’s Conference of the Moscow Institute of Fine Chemical Technology (Moscow, 1971), p. 18 [in Russian].

  4. P. P. Fedorov, Russ. J. Inorg. Chem. 55, 1722 (2010).

    Article  CAS  Google Scholar 

  5. P. P. Fedorov, Proceedings of the 17th International Conference on Chemical Thermodynamics in Russia (RCCT), 2009.

  6. V. V. Kosyakov and P. P. Fedorov, Proceedings of the 9th Kurnakov’s International Congress on Physicochemical Analysis, Perm, 2010 (Perm, 2010), p. 53 [in Russian].

  7. G. B. Bokii, Zh. Neorg. Khim. 1, 1599 (1956).

    CAS  Google Scholar 

  8. G. B. Bokii, Crystal Chemistry (Nauka, Moscow, 1971) [in Russian].

    Google Scholar 

  9. E. S. Makarov, Atomic Isomorphism in Crystals (Atomizdat, Moscow, 1973) [in Russian].

    Google Scholar 

  10. N. N. Sirota, The Physicochemical Nature of Phases of Variable Composition (Nauka i tekhnika, Minsk, 1970) [in Russian].

    Google Scholar 

  11. V. I. Mikheeva, Methods of Physicochemical Analysis in Inorganic Synthesis (Nauka, Moscow, 1975) [in Russian].

    Google Scholar 

  12. Yu. G. Zainulin, S. I. Alyamovskii, and G. P. Shveikin, Zh. Neorg. Khim. 25, 599 (1980).

    CAS  Google Scholar 

  13. N. S. Kurnakov and V. I. Mikheeva, Izv. Akad. Nauk SSSR, Ser. Khim. 2, 259 (1937).

    Google Scholar 

  14. P. P. Fedorov, Russ. J. Phys. Chem. 73, 1381 (1999).

    Google Scholar 

  15. B. P. Sobolev and K. B. Seiranyan, Kristallografiya 20, 763 (1975).

    CAS  Google Scholar 

  16. P. P. Fedorov and B. P. Sobolev, Soviet Physics-Crystallography 20, 584 (1975).

    Google Scholar 

  17. B. P. Sobolev, V. B. Aleksandrov, P. P. Fedorov, et al., Soviet Physics-Crystallography 21, 49 (1976).

    Google Scholar 

  18. B. P. Sobolev, P. P. Fedorov, D. B. Steynberg, et al., J. Solid State Chem. 17(1/2), 191 (1976).

    Article  CAS  Google Scholar 

  19. B. P. Sobolev and P. P. Fedorov, J. Less-Common Met. 60, 33 (1978).

    Article  CAS  Google Scholar 

  20. P. P. Fedorov and B. P. Sobolev, J. Less-Common Met. 63(1), 31 (1979).

    Article  CAS  Google Scholar 

  21. B. P. Sobolev, The Rare Earth Trifluorides, Part 1: The High-Temperature Chemistry of the Rare Earth Trifluorides (Barcelona, 2000).

  22. I. I. Buchinskaya and P. P. Fedorov, Russ. Chem. Rev. 73, 371 (2004).

    Article  CAS  Google Scholar 

  23. P. P. Fedorov and B. P. Sobolev, Crystallography Reports 40, 284 (1995).

    Google Scholar 

  24. P. P. Fedorov, Russ. J. Inorg. Chem. 44, 1703 (1999).

    Google Scholar 

  25. P. P. Fedorov and B. P. Sobolev, Russ. J. Inorg. Chem. 24, 574 (1979).

    Google Scholar 

  26. P. P. Fedorov, Russ. J. Inorg. Chem. 45(Suppl. 3), 268 (2000).

    Google Scholar 

  27. P. P. Fedorov, Russ. J. Phys. Chem. 73, 1387 (1999).

    Google Scholar 

  28. L. N. Pavlova, P. P. Fedorov, L. A. Ol’khovaya, et al., Russ. J. Inorg. Chem. 34, 1234 (1989).

    Google Scholar 

  29. P. P. Fedorov, L. N. Pavlova, L. A. Ol’khovaya, et al., Russ. J. Inorg. Chem. 35, 1676 (1990).

    Google Scholar 

  30. P. P. Fedorov, I. I. Buchinskaya, O. S. Bondareva, et al., Russ. J. Inorg. Chem. 41, 823 (1996).

    Google Scholar 

  31. R. E. Thoma, H. Insley, and G. M. Hebert, Inorg. Chem. 5, 1222 (1966).

    Article  CAS  Google Scholar 

  32. P. P. Fedorov, V. B. Alexsandrov, O. S. Bondareva, et al., Crystallography Reports 46, 239 (2001).

    Article  Google Scholar 

  33. M. Zinkevich, Progr. Mater. Sci. 52, 597 (2007).

    Article  CAS  Google Scholar 

  34. O. V. Andreev, Doctoral Dissertation in Chemistry (Tyumen State Univ., Tyumen, 1999).

    Google Scholar 

  35. S. S. Sikerin, Candidate Dissertation in Physics and Mathematics (Tyumen State Univ., Tyumen, 2000.

    Google Scholar 

  36. O. V. Andreev, N. N. Parshukov, A. V. Kertman, and T. M. Kislovskaya, Russ. J. Inorg. Chem. 41, 284 (1996).

    Google Scholar 

  37. S. A. Ivakhnenko and E. G. Ponyatovskii, Fiz. Met. Metalloved. 47, 809 (1979).

    CAS  Google Scholar 

  38. E. Yu. Tonkov, High-Pressure Phase Diagrams of the Elements (Nauka, Moscow, 1979) [in Russian].

    Google Scholar 

  39. I. L. Aptekar’ and V. B. Baskakova, Dokl. Akad. Nauk SSSR 191, 1305 (1970).

    Google Scholar 

  40. D. T. Peterson and V. G. Fattore, J. Phys. Chem. 65, 2062 (1961).

    Article  CAS  Google Scholar 

  41. V. S. Sidorov, P. P. Fedorov, D. D. Ikrami, and B. P. Sobolev, Proceedings of the 5th All-Union Symposium on the Chemistry of Inorganic Fluorides (Nauka, Moscow, 1978), p. 258 [in Russian].

    Google Scholar 

  42. E. I. Ardashnikova, M. P. Borzenkova, and A. V. Novoselova, Zh. Neorg. Khim. 34, 1303 (1989).

    CAS  Google Scholar 

  43. E. I. Ardashnikova, M. P. Borzenkova, and N. V. Borovskikh, Zh. Neorg. Khim. 34, 992 (1989).

    CAS  Google Scholar 

  44. V. Leute, A. Behr, C. Hunting, and H. M. Schmidtke, Solid State Ionics 68, 287 (1994).

    Article  CAS  Google Scholar 

  45. D. D. Ikrami, P. P. Fedorov, A. A. Luginina, and L. A. Ol’khovaya, Zh. Neorg. Khim. 30, 1261 (1985).

    CAS  Google Scholar 

  46. P. P. Fedorov, L. V. Medvedeva, and B. P. Sobolev, Russ. J. Phys. Chem. 76, 337 (2002).

    Google Scholar 

  47. D. A. Petrov, Zh. Fiz. Khim. 21, 785 (1947).

    CAS  Google Scholar 

  48. R. S. Bubnova, S. K. Filatov, and R. G. Grebenshchikov, Dokl. Akad. Nauk SSSR 292(1), 107 (1987).

    CAS  Google Scholar 

  49. L. A. Ol’khovaya, G. A. Karpenko, D. D. Ikrami, and P. P. Fedorov, Russ. J. Inorg. Chem. 36, 1639 (1991).

    Google Scholar 

  50. P. P. Fedorov, A. V. Andreev, T. V. Zimina, and B. P. Sobolev, Russ. J. Inorg. Chem. 37, 967 (1992).

    Google Scholar 

  51. P. P. Fedorov and A. V. Rappo, Russ. J. Inorg. Chem. 53, 11126 (2008).

    Google Scholar 

  52. P. Quintana and A. R. West, J. Solid State Chem. 81(2), 257 (1989).

    Article  CAS  Google Scholar 

  53. L. M. Lopato, A. V. Shevchenko, A. E. Kushchevskii, and S. G. Tresvyatstkii, Izv. Akad. Nauk SSSR, Neorg. Mater. 10, 1481 (1974).

    CAS  Google Scholar 

  54. R. S. Bubnova and S. K. Filatov, The High-Temperature Crystal Chemistry of Borates and Borosilicates (Nauka, St. Petersburg, 2008) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Prokhorov General Physics Institute, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    P. P. Fedorov

Authors
  1. P. P. Fedorov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. P. Fedorov.

Additional information

Original Russian Text © P.P. Fedorov, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 7, pp. 1033–1043.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fedorov, P.P. Berthollide formation conditions. Russ. J. Inorg. Chem. 57, 959–969 (2012). https://doi.org/10.1134/S003602361207011X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602361207011X

Keywords

Search

Navigation