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Synthesis and crystal structure of the complex N,N-dimethylanilinium dicitratoborate monohydrate

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Abstract

N,N-Dimethylanilinium dicitratoborate monohydrate [C6H5NH(CH3)2][(C6H6O7)2B]·H2O (I) was synthesized for the first time. Single crystals were obtained in an aqueous solution; the crystal structure was studied by X-ray crystallography. Crystals of I are triclinic, space group \(P\bar 1\), a = 9.7017(2) Å, b = 11.0475(2) Å, c = 12.6282(2) Å, α = 106.595(2)°, β = 106.931(1)°, Γ = 103.568(1)°, V = 1163.97(4) Å3, Z = 2, ρcalc = 1.516 g/cm3. The structural units of compound 1 are large complex dicitratoborate anions with a spiran structure, N,N-dimethylanilinium cations, and crystal water molecules. The crystal packing is a three-dimensional framework. A hydrogen-bond system is formed by seven independent contacts O(N)-H…O.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry of the Riga Technical University, Miera iela 34, Salaspils-1, Riga Distr., LV-2169, Latvia

    I. I. Zviedre

  2. Latvian Institute of Organic Synthesis, Aizkraukles iela 21, Riga, LV-1006, Latvia

    S. V. Belyakov

Authors
  1. I. I. Zviedre
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  2. S. V. Belyakov
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Original Russian Text © I.I. Zviedre, S.V. Belyakov, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 10, pp. 1433–1439.

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Zviedre, I.I., Belyakov, S.V. Synthesis and crystal structure of the complex N,N-dimethylanilinium dicitratoborate monohydrate. Russ. J. Inorg. Chem. 57, 1348–1354 (2012). https://doi.org/10.1134/S0036023612060290

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  • DOI: https://doi.org/10.1134/S0036023612060290

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