Skip to main content
SpringerLink
Log in

Synthesis of TiO2-SiO2 xerogels via the hydrolysis of a tetrabutoxytitanium-tetraethoxysilane mixture in aqueous ammonia and hydrochloric acid atmospheres

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

TiO2-SiO2 xerogels have been synthesized by the hydrolysis of tetrabutoxytitanium-tetraethoxysilane mixtures in a 10% aqueous ammonia vapor and concentrated hydrochloric acid vapor atmospheres under static conditions. The dependence of the physical and chemical properties of the xerogels on the synthetic conditions has been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. P. Fedotova, G. A. Voronova, E. Yu. Emel’yanova, et al., Russ. J. Phys. Chem. A 83(8), 1371 (2009).

    Article  CAS  Google Scholar 

  2. O. A. Kholdeeva and N. N. Trukhan, Usp. Khim. 75, 460 (2006).

    Google Scholar 

  3. N. V. Lebukhova, V. S. Rudnev, P. G. Chigrin, et al., Khim. Tekhnol., No. 12, 740 (2010).

  4. G. G. Kozlov, V. S. Zapasskii, and V. V. Ovsyankin, Opt. Spectrosc. 109(3), 397 (2010).

    Article  CAS  Google Scholar 

  5. O. A. Kholdeeva, I. D. Ivanchikova, M. Guidotti, and N. Ravasio, Green Chem. 9, 731 (2007).

    Article  CAS  Google Scholar 

  6. A. J. Bonon, D. Mandelli, O. A. Kholdeeva, et al., Appl. Catal., A 365, 96 (2009).

    Article  CAS  Google Scholar 

  7. Changzi Jin, Gang Li, Xiangsheng Wang, et al., Microporous Mesoporous Mater. 111, 236 (2008).

    Article  CAS  Google Scholar 

  8. L. J. Bellami, The Infra-Red Spectra of Complex Molecules (Wiley, New York, 1960; Inostrannaya Literatura, Moscow, 1963).

    Google Scholar 

  9. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds (Wiley, New York, 1963; Mir, Moscow, 1966).

    Google Scholar 

  10. V. E. Eremyashev, Candidate’s Dissertation in Engineering (South Ural State Univ., Chelyabinsk, 2007).

    Google Scholar 

  11. S. A. Emralieva, Doctoral Dissertation in Chemistry (South Ural State Univ., Chelyabinsk, 2009).

    Google Scholar 

  12. R. V. Sazonov, Candidate’s Dissertation in Physics & Mathematics (Tomsk Polytechnic Univ., Tomsk, 2010).

    Google Scholar 

  13. M. P. Fedotova, Candidate’s Dissertation in Chemistry (Tomsk, 2009).

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Akademicheskaya ul. 22/20, Yekaterinburg, 620990, Russia

    A. B. Shishmakov, Yu. V. Mikushina, O. V. Koryakova, M. S. Valova & L. A. Petrov

  2. Ural State University of Wood Chemistry, ul. Sibirskii Trakt 37, Yekaterinburg, 620100, Russia

    S. A. Melkozerov

Authors
  1. A. B. Shishmakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. V. Mikushina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Koryakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. S. Valova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. A. Petrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. A. Melkozerov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. V. Mikushina.

Additional information

Original Russian Text © A.B. Shishmakov, Yu.V. Mikushina, O.V. Koryakova, M.S. Valova, L.A. Petrov, S.A. Melkozerov, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 6, pp. 857–863.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shishmakov, A.B., Mikushina, Y.V., Koryakova, O.V. et al. Synthesis of TiO2-SiO2 xerogels via the hydrolysis of a tetrabutoxytitanium-tetraethoxysilane mixture in aqueous ammonia and hydrochloric acid atmospheres. Russ. J. Inorg. Chem. 57, 787–793 (2012). https://doi.org/10.1134/S0036023612060198

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023612060198

Keywords

Search

Navigation