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Synthesis and characterization of a new octamolybdate (NH4)4[Mo8O24(C3H2O2)2] · 4H2O

  • Physical Methods of Investigation
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Abstract

A new complex with the formula (NH4)4[Mo8O24(C3H2O2)2] · 4H2O (1) has been synthesized and characterized by single crystal X-ray diffraction and infrared spectrum. The complex is small yellow crystal and space group P 1 with a = 9.9869(18) Å, b = 10.030(19) Å, c = 10.366(19) Å, α = 91.68(3)°, β = 98.94(3)°, γ = 119.37(2)°, V = 887(3) Å3, and Z = 1. The complex contains two malonic acid ligands bonded to the γ-Mo8 4−26 ions which consist of eight MoO6 edge-sharing octahedral. In this crystal structure, the octamolybdate anion is mutually hydrogen bonded by ammonium ions and water molecules.

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Authors and Affiliations

  1. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining Qinghai province, 81008, P. R. China

    Shoujiang Wang

  2. Dongguan University of Technology, Dongguan, 523808, P. R. China

    Shaofen Mo

  3. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, P. R. China

    Zhen-Gang Liu

Authors
  1. Shoujiang Wang
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  2. Shaofen Mo
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  3. Zhen-Gang Liu
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Correspondence to Shoujiang Wang.

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Wang, S., Mo, S. & Liu, ZG. Synthesis and characterization of a new octamolybdate (NH4)4[Mo8O24(C3H2O2)2] · 4H2O. Russ. J. Inorg. Chem. 57, 430–433 (2012). https://doi.org/10.1134/S0036023612030266

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  • DOI: https://doi.org/10.1134/S0036023612030266

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