Abstract
Binuclear copper(II) complexes with acyldihydrazones of benzenedicarboxylic acid and trifluoroacetylacetone have been synthesized and studied. The structure of the copper(II) complex with diacylhydrazone of 1,3-benzenedicarboxylic acid (H4L) of composition [Cu2L · 2LPy] has been studied by X-ray diffraction. The crystals are triclinic: a = 9.2298(4) Å, b = 11.8510(6) Å, c = 13.8314(7) Å, α = 90.780(3)°, β = 96.124(3)°, γ = 99.264(3)°, space group \(P\bar 1\), Z = 2. The number of symmetry-unrelated reflections with I > 2σ(I) 5941; R = 0.0357, R w = 0.0589. The complex contains two equivalent copper atoms at a distance of 9.56 Å from each other in the square-planar coordination environment. The high-temperature EPR spectra of the complexes show a signal of seven HFS lines indicating the coupling of unpaired electrons to two equivalent copper nuclei (g = 2.113−2.116, a Cu = 37.0−37.2 × 10−4 cm−1).
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Original Russian Text © V.F. Shul’gin, Yu.V. Trush, O.V. Konnik, E.B. Rusanov, V.Ya. Zub, V.V. Minin, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 2, pp. 270–275.
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Shul’gin, V.F., Trush, Y.V., Konnik, O.V. et al. Structure and EPR spectra of binuclear copper(II) complexes with acyldihydrazones of benzenedicarboxylic acids and trifluoroacetylacetone. Russ. J. Inorg. Chem. 57, 226–230 (2012). https://doi.org/10.1134/S0036023612020234
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DOI: https://doi.org/10.1134/S0036023612020234