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Synthesis and study of (CN3H6)2[(UO2)2(C2O4)(SeO3)2] by IR spectroscopy and X-ray diffraction

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Abstract

Single crystals of (CN3H6)2[(UO2)2(C2O4)(SeO3)2] were synthesized and studied by IR spectroscopy and X-ray diffraction. The compound crystallizes in the triclinic system with the unit cell parameters a = 7.1169(12) Å, b = 7.4874(10) Å, c = 8.9748(14) Å, α = 88.243(6)°, β = 74.546(6)°, γ = 81.445(6)°, space group \(P\bar 1\), Z = 1, R = 0.0304. The main structural units of the crystals are layers of the [(UO2)2(C2O4)(SeO3)2]2− composition; the layers belong to the crystal chemical group A 2 K 02 T 32 (A = UO 2+2 K 02 = C2O 2−4 , T 3 = SeO –3 ) of uranyl complexes. Uranium-containing complex groups are linked by electrostatic interactions and a network of hydrogen bonds with CN3H +6 guanidinium ions to form a three-dimensional framework.

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Authors and Affiliations

  1. Samara State University, ul. Akademika Pavlova, 1, Samara, 443011, Russia

    D. V. Pushkin, L. B. Serezhkina, A. V. Savchenkov & V. N. Serezhkin

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. V. Peresypkina & A. V. Virovets

Authors
  1. D. V. Pushkin
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  2. E. V. Peresypkina
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  3. L. B. Serezhkina
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  4. A. V. Savchenkov
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  5. A. V. Virovets
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  6. V. N. Serezhkin
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Original Russian Text © D.V. Pushkin, E.V. Peresypkina, L.B. Serezhkina, A.V. Savchenkov, A.V. Virovets, V.N. Serezhkin, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 2, pp. 216–221.

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Pushkin, D.V., Peresypkina, E.V., Serezhkina, L.B. et al. Synthesis and study of (CN3H6)2[(UO2)2(C2O4)(SeO3)2] by IR spectroscopy and X-ray diffraction. Russ. J. Inorg. Chem. 57, 175–180 (2012). https://doi.org/10.1134/S0036023612020210

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  • DOI: https://doi.org/10.1134/S0036023612020210

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