Skip to main content
SpringerLink
Log in

Synthesis, structure, and reactions of iridium(I) complexes with 5,10,15,20-tetraphenyl-21H,23H-porphine and 5,10,15,20-tetraphenyl-21H,23H-porphine dianion

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

One-step joint synthesis of two iridium porphyrin complexes, a donor-acceptor SAT (sitting a top) complex μ-(5,10,15,20-tetraphenylporphine)-bis-chloroiridium(I) and the covalent complex (5,10,15,20-tetraphenylporphinato)chloroiridium(III) by the reaction of free porphyrin and chloroiridic acid (H3O)2IrCl6 in boiling phenol was studied. The structure of complexes was confirmed by spectroscopy (UV/Vis, IR, 1H NMR) and TLC. The iridium(III) SAT complex with the hydride ligand in the first coordination sphere, (acetato)hydrido(5,10,15,20-tetraphenylporphine)iridium(III), was obtained by oxidative addition reaction, which is quite rare for porphyrin complexes. The thermodynamic stability of the complexes to oxidants (aerated acids) was studied by spectrophotometric titration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. P. Solov’ev, M. S. Stuklova, E. V. Kotlunova, and N. N. Kochanova, Russ. J. Coord. Chem. 29(9), 660 (2003).

    Article  Google Scholar 

  2. A. Antipes and M. Gouterman, J. Am. Chem. Soc. 105, 4896 (1983).

    Article  Google Scholar 

  3. J. W. Buchler, Struct. Bonding 84, 206 (1995).

    Google Scholar 

  4. A. A. Grinberg, Introduction to the Chemistry of Complex Compounds (Khimiya, Moscow, 1966) [in Russian].

    Google Scholar 

  5. J. H. Palmer, M. W. Day, A. D. Wilson, et al., J. Am. Chem. Soc. 130, 7786 (2008).

    Article  CAS  Google Scholar 

  6. Toganoh Motoki, Konagawa Jo, and Furuta Hiroyuki, Inorg. Chem. 45, 3852 (2006).

    Article  Google Scholar 

  7. S. Matthias, W. L. Karney, S. I. Khan, and C. S. Foote, Inorg. Chem. 34, 5715 (1995).

    Article  Google Scholar 

  8. T. N. Lomova, Doctoral Dissertation in Chemistry (IKhR RAN, Ivanovo, 1990).

    Google Scholar 

  9. T. N. Lomova, in Progress in Porphyrin Chemistry (Izd. SPb. Gos. Univ., St. Petersburg, 2001), vol. 3, p. 233 [in Russian].

    Google Scholar 

  10. T. N. Lomova, O. V. Molodkina, and E. G. Mozhzhukhina, Izv. Akad. Nauk, Ser. Khim., 2052 (1998).

  11. H. Ogoshi, Setsune Jun-Ichino, T. Omura, and Yoshida Zen-Ichi, J. Am. Chem. Soc. 97, 6461 (1975).

    Article  CAS  Google Scholar 

  12. M. E. Klyueva, T. N. Lomova, B. D. Berezin, and A. S. Semeikin, Russ. J. Inorg. Chem. 48, 1238 (2003).

    Google Scholar 

  13. Yu. N. Kukushkin, Reactivity of Coordination Compounds (Khimiya, Leningrad, 1987) [in Russian].

    Google Scholar 

  14. T. N. Lomova, N. I. Volkova, and B. D. Berezin, Zh. Neorg. Khim. 32, 696 (1987).

    Google Scholar 

  15. T. N. Lomova, Basics of Synthesis and Mechanisms of Transformations of Porphyrins and Their Analogues (Izd. Ivanovsk. Gos. Khim.-Tekhnol. Uuiv., Ivanovo, 2006), Part 1 [in Russian].

    Google Scholar 

  16. K. M. Kadish, Y. Y. Deng, C.-L. Yao, and J. E. Anderson, Organometallica 7, 1979 (1988).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya 1, Ivanovo, 153045, Russia

    T. N. Lomova & E. G. Mozhzhukhina

Authors
  1. T. N. Lomova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. G. Mozhzhukhina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. N. Lomova.

Additional information

Original Russian Text © T.N. Lomova, E.G. Mozhzhukhina, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 2, pp. 239–246.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lomova, T.N., Mozhzhukhina, E.G. Synthesis, structure, and reactions of iridium(I) complexes with 5,10,15,20-tetraphenyl-21H,23H-porphine and 5,10,15,20-tetraphenyl-21H,23H-porphine dianion. Russ. J. Inorg. Chem. 57, 197–204 (2012). https://doi.org/10.1134/S0036023612020155

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023612020155

Keywords

Search

Navigation