Abstract
A methodology for determining hidden partitioning elements while differentiating complexing multicomponent systems was developed using exchange reactions in ternary mutual systems and tested on ten quaternary mutual systems. For the first time, using a combination of such physicochemical analysis methods as differential thermal, X-ray powder diffraction, and projection-thermographic analyses, the LiF-K2WO4-CaF2-BaF2 quaternary system was studied, which involves the hidden partitioning element K2WO4-LiBaF3 and is a stable partitioning complex of the Li,K,Ca,Ba∥F,WO4 quinary mutual system. The coordinates of nonvariant points of the quaternary system were found.
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References
N. S. Kurnakov, Introduction to Physicochemical Analysis, Ed. by V. Ya. Anosov and M. A. Klochko (Izd. AN SSSR, Moscow-Leningrad, 1940) [in Russian].
V. Ya. Anosov and S. A. Pogodin, Fundamentals of Physicochemical Analysis (Izd. Akad. Nauk. SSSR, Moscow, 1947) [in Russian].
V. P. Radishchev, Multicomponent Systems (Izd. AN SSSR, Moscow, 1964) [in Russian].
A. G. Bergman, V. P. Radishchev, and I. S. Dombrovskaya, Dokl. Akad. Nauk SSSR 77, 811 (1951).
A. M. Gasanaliev, Doctoral Dissertation in Chemistry (Tashkent, 1990).
L. Soliev, Available from VINITI, 1987, no. 8990-V87.
F. M. Perel’man, Visualization of Chemical Systems with an Arbitrary Number of Components (Nauka, Moscow, 1965) [in Russian].
Zh. A. Kochkarov, Doctoral Dissertation in Chemistry (KBGU, Nal’chik, 2001).
A. V. Chuvakov, Extended Abstract of Candidate’s Dissertation in Chemistry (SGTU, Samara, 2007).
V. I. Posypaiko, Dortoral Dissertation in Chemistry (VZPI, Moscow, 1964).
G. E. Dmitrenko, in Problems of Applied Geometry (Izd. MAI, Moscow, 1966), p. 172 [in Russian].
P. A. Akhmedova, Candidate’s Dissertation in Chemistry (DGU, Makhachkala, 2002).
B. Yu. Gamataeva, Candidate’s Dissertation in Chemistry (IONKh, Moscow, 1995).
N. N. Verdiev, Candidate’s Dissertation in Chemistry (KPtI i Dagestanskii filial gosudarstvennogo nauchnoissledovatel’skogo energeticheskogo instituta, Makhachkala, 1989).
A. M. Gasanaliev, P. A. Akhmedova, and B. Yu. Gamataeva, Available from VINITI, 2010, no. 328-V2010.
A. G. Bergman, Proceedings of IV Mendeleev Congress on Theoretical and Applied Chemitry (Moscow, 1932), No. 1, p. 631 [in Russian].
W. W. Wendland, Thermal Analysis (Wiley, New York, 1986; Mir, Moscow, 1978).
A. S. Kosmynin, Extended Abstract of Candidate’s Dissertation in Chemistry (IONKh, Moscow, 1977).
L. G. Berg, Introduction to Thermal Analysis (Nauka, Moscow, 1969) [in Russian].
V. K. Trunov and L. M. Kovba, X-ray Diffraction Analysis (Mosk. Gos. Univ., Moscow, 1976).
L. I. Mirkin, A Handbook on X-ray Diffraction Analysis of Polycrystals (Fizmatgiz, Moscow, 1961) [in Russian].
R. A. Giller, Tablitsy mezhploskostnykh rasstoyanii (Nedra, Moscow, 1966), Vol. 2 [in Russian].
Index Powder Diffraction Files (ASTM, New York, 1975).
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Original Russian Text © A.M. Gasanaliev, P.A. Akhmedova, B.Yu. Gamataeva, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 2, pp. 319–329.
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Gasanaliev, A.M., Akhmedova, P.A. & Gamataeva, B.Y. Methodology for determining hidden partitioning elements in mutual multicomponent systems and physicochemical interactions in the LiF-K2WO4-CaF2-BaF2 system. Russ. J. Inorg. Chem. 57, 274–283 (2012). https://doi.org/10.1134/S0036023612020088
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DOI: https://doi.org/10.1134/S0036023612020088