Skip to main content

Cleavage of the cyclic substituent in the [B10H9O2C4H8]−, [B10H9OC4H8]−, and [B10H9OC5H10]− anions upon the interaction with negatively charged N-nucleophiles

Russian Journal of Inorganic Chemistry volume 56, pages 1549–1554 (2011)Cite this article

Abstract

The interaction of the [B10H9O2C4H8]−, [B10H9OC4H8]−, and [B10H9OC5H10]− anions with negatively charged N-nucleophiles has been studied. It has been shown that such reactions yield doubly charged substituted closo-decaborates with a nitrogen-containing group attached to the cluster through an alkoxyl spacer. Compounds with pendant NO2 −, N3 −, N(CO)2C6H4 −, and NHC6H5 groups have been synthesized.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. I. B. Sivaev, A. A. Semioshkin, B. Brellochs, et al., Polyhedron 19(6) (2000).

  2. T. Peymann, K. Kiick, and D. Gabel, Inorg. Chem. 36, 22 (1997).

    Article  Google Scholar 

  3. K. Yu. Zhizhin, V. N. Mustyatsa, E. A. Malinina, et al., Russ. J. Inorg. Chem. 50(2), 203 (2005).

    Google Scholar 

  4. E. Yu. Matveev, G. A. Razgonyaeva, V. N. Mustyatsa, et al., Izv. Akad. Nauk, Ser. Khim., 544 (2010).

  5. Ya. Z. Voloshin, O. A. Varzatskii, K. Yu. Zhizhin, and N. T. Kuznetsov, Proceedings of XXIII International Chugaev Conference, Odessa, 2007, p. 29.

  6. Ya. Z. Voloshin, O. A. Varzatskii, K. Yu. Zhizhin, and Yu. N. Bubnov, Izv. Akad. Nauk, Ser. Khim., 555 (2007).

  7. R. Bernard, D. Cornu, M. Perrin, et al., J. Organomet. Chem. 689, 2581 (2004).

    Article  CAS  Google Scholar 

  8. J. March, Advanced Organic Chemistry (Wiley, New York, 1985; Mir, Moscow, 1987), Vol. 2.

    Google Scholar 

  9. K. Yu. Zhizhin, V. N. Mustyatsa, E. A. Malinina, et al., Russ. J. Inorg. Chem. 49(2), 180 (2004).

    Google Scholar 

  10. H. Becker, W. Berger and G. Domschke, Organikum: Organisch-chemisches Grundpraktikum (VEB Deutscher Verlag der Wissenschaften, Berlin, 1990; Mir, Moscow, 1992).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. Yu. Matveev, V. M. Retivov, G. A. Razgonyaeva, K. Yu. Zhizhin & N. T. Kuznetsov

  2. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia

    E. Yu. Matveev, K. Yu. Zhizhin & N. T. Kuznetsov

Authors
  1. E. Yu. Matveev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Retivov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. A. Razgonyaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. Yu. Zhizhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. T. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. Yu. Matveev.

Additional information

Original Russian Text © E.Yu. Matveev, V.M. Retivov, G.A. Razgonyaeva, K.Yu. Zhizhin, N.T. Kuznetsov, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 10, pp. 1628–1633.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Matveev, E.Y., Retivov, V.M., Razgonyaeva, G.A. et al. Cleavage of the cyclic substituent in the [B10H9O2C4H8]−, [B10H9OC4H8]−, and [B10H9OC5H10]− anions upon the interaction with negatively charged N-nucleophiles. Russ. J. Inorg. Chem. 56, 1549–1554 (2011). https://doi.org/10.1134/S0036023611100160

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023611100160

Keywords

  • Boron Neutron Capture Therapy
  • Anionic Part
  • Tetraphenylphosphonium
  • Cationic Part
  • Viscous Substance