Abstract
A new complex approach to determine absolute partial pressures of molecular and ionic components of vapor is advanced on the basis of a combination of mass-spectrometric and quantum-chemical methods using sodium bromide as an example. Thermodynamic parameters of molecules and ions and the electron work function are determined for crystalline NaBr.
Similar content being viewed by others
References
L. N. Sidorov, M. V. Korobov, and L. V. Zhuravleva, Mass-Spectroscopic Thermodynamic Investigations (Izd-vo Mosk. Univ., Moscow, 1985) [in Russian].
S. V. Abramov, N. S. Chilingarov, A. Ya. Borshchevsky, and L. N. Sidorov, Int. J. Mass Spectrom. Ion Processes 231, 31 (2004).
L. S. Kudin, A. V. Gusarov, L. N. Gorokhov, and K. S. Krasnov, Teplofiz. Vys. Temp. 13(4), 735 (1975).
H. Wartenberg and P. Z. Albrecht, Elektrochem. 27, 162 (1921).
J. E. Mayer and I. H. Wintner, J. Chem. Phys. 6, 301 (1938).
K. Niwa, J. Chem. Soc. Jpn. 59, 637 (1938).
H. Bloom, J. Bockris, N. Richards, and R. Taylor, J. Am. Chem. Soc. 80, 2044 (1958).
I. G. Murgulescu and L. Topor, Rev. Roum. Chim. 11, 1353 (1966).
J. Berkowitz and W. A. Chupka, J. Chem. Phys. 29, 653 (1958).
The Thermodynamic Properties of Individual Substances. Reference Book, Ed. by V. P. Glushko (Nauka, Moscow, 1978–1984) [in Russian].
A. M. Pogrebnoi, L. S. Kudin, A. Yu. Kuznetsov, and M. F. Butman, Rap. Comm. Mass Spec. 11, 1536 (1997).
M. F. Butman, L. S. Kudin, A. E. Grishin, et al., Zh. Fiz. Khim. 82(3), 545 (2008) [Russ. J. Phys. Chem. 82 (3), 459 (2008)].
Yu. N. Malov, L. S. Leonova, S. E. Nadkhina, et al., Zh. Fiz. Khim. 56(8), 1879 (1982).
A. D. Becke, J. Chem. Phys. 98, 5648 (1993).
P. J. Stephens, F. J. Devlin, C. F. Ghablowski, and M. J. Frisch, J. Phys. Chem. 98, 11623 (1994).
R. H. Hertwig and W. Koch, Chem. Phys. Lett. 268, 345 (1997).
M. Dolg, H. Stoll, A. Savin, and H. Preuss, Theor. Chim. Acta 75, 4173 (1989).
A. Bergner, M. Dolg, W. Kuechle, et al., Mol. Phys. 80, 1431 (1993).
The Extensible Computational Chemistry Environment Basis Set Database, Version 6/19/03, developed and distributed by the Molecular Science Computing Facility, Environmental and Molecular Sciences Laboratory, P.O. Box 999, Richland, Washington 99352, USA, and funded by the U.S. Department of Energy.
J. M. L. Martin and A. Sundermann, J. Chem. Phys. 114(8), 3408 (2001).
V. G. Solomonik and O. Yu. Marochko, Zh. Strukt. Khim. 41(5), 885 (2000).
M. F. Butman, V. V. Sliznev, and L. S. Kudin, Zh. Fiz. Khim. 76(1), 18 (2002) [Russ. J. Phys. Chem. 76 (1), 14 (2002)].
E. Ya. Zandberg and N. I. Ionov, Surface Ionization (Nauka, Moscow, 1969) [in Russian].
L. V. Gurvich, G. V. Karachevtsev, V. N. Kondrat’ev, et al., The Energies of Rupture of Chemical Bonds. Ionization Potentials and Electron Affinity. Handbook (Nauka, Moscow, 1974) [in Russian].
Author information
Authors and Affiliations
Additional information
Original Russian Text © L.S. Kudin, D.A. Ivanov, M.F. Butman, A.M. Dunaev, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 8, pp. 1382–1387.
Rights and permissions
About this article
Cite this article
Kudin, L.S., Ivanov, D.A., Butman, M.F. et al. New approach to determine absolute partial pressures of ions in saturated vapors of inorganic materials. Russ. J. Inorg. Chem. 56, 1312–1317 (2011). https://doi.org/10.1134/S0036023611080134
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023611080134