Skip to main content
SpringerLink
Log in

Synthesis and crystal structure of nickel(II) dinitrate molecular complex with 3,5-lutidine

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Complex [Ni(NO3)2(3,5-lutidine)3] (3,5-lutidine, 3,5-Lut-C7H9N) was synthesized, and its crystal structure was determined. Complex crystals are monoclinic: space group Cc, a = 14.445(1) Å, b = 10.024(1) Å, c = 17.607(1) Å, β = 108.96(1)°, V = 2411(1) Å3, ρcalcd = 2.389 g/cm3, Z = 4. The structure is built of discrete neutral complexes [Ni(3,5-Lut)3(NO3)2]. The coordination sphere of Ni2+ ions is a disordered octahedron, which consists of three crystallographically nonequivalent lutidine ligands (Ni-N, 2.059–2.124 Å) and two oxygen ions of the two nitrate ions (Ni-O, 2.047–2.258 Å).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. R. Desiraju, Angew. Chem. Int. Ed. Eng. 34, 2311 (1995).

    Article  CAS  Google Scholar 

  2. M. Eddaouddi, D. B. Moler, H. Li, et al., Acc. Chem. Res. 34(4), 319 (2001).

    Article  Google Scholar 

  3. R. V. Biagetti and H. M. Haendler, Inorg. Chem. 5, 383 (1966).

    Article  CAS  Google Scholar 

  4. M. R. Rosenthal and R. S. Drago, Inorg. Chem. 4, 840 (1965).

    Article  CAS  Google Scholar 

  5. A. F. Cameron, D. W. Taylor, and R. H. Nuttall, J. Chem. Soc., Dalton Trans., 1603 (1972).

  6. C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 375 (1999).

  7. K. N. Power, T. L. Hennigar, and M. J. Zaworotko, New J. Chem., 177 (1998).

  8. Yu. V. Kokunov, V. V. Kovalev, and Yu. E. Gorbunova, Koord. Khim. 34(12), 913 (2008).

    Google Scholar 

  9. G. M. Sheldrick, SHELXS97. Program for the Solution of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  10. G. M. Sheldrick, SHELXL97. Program for the Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  11. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley, New York, 1986; Mir, Moscow, 1991).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    Yu. V. Kokunov, Yu. E. Gorbunova & V. V. Kovalev

Authors
  1. Yu. V. Kokunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. E. Gorbunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Kovalev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © Yu.V. Kokunov, Yu.E. Gorbunova, V.V. Kovalev, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 6, pp. 914–918.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kokunov, Y.V., Gorbunova, Y.E. & Kovalev, V.V. Synthesis and crystal structure of nickel(II) dinitrate molecular complex with 3,5-lutidine. Russ. J. Inorg. Chem. 56, 856–860 (2011). https://doi.org/10.1134/S0036023611060118

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023611060118

Keywords

Search

Navigation