Skip to main content
SpringerLink
Log in

Synthesis and crystal structure of a new ternary intermetallic compound Ce16Ru8 + x In3 − x (0 < x < 1.0)

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

A study of phase equilibria in the Ce-Ru-In ternary system showed the presence of a new ternary compound Ce16Ru8+x In3−x , which exists in the range of 0 < x < 1.0. According to a single-crystal X-ray diffraction study of Ce16Ru8+x In3−x (x = 0.29), this compound crystallizes in the tetragonal system and represents a new structural type: a = 11.8047(15) Å, c = 9.5464(13) Å, space group. P4/mbm, Z = 2, R F = 0.059, R w = 0.124. A specific feature of this structure is the presence of short Ce-Ru distances (2.575(3)Å).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. O. Trovarelli, C. Geibel, S. Mederle, et al., Phys. Rev. Lett. 85, 626 (2000).

    Article  CAS  Google Scholar 

  2. N. D. Mathur, F. M. Grosche, S. R. Julian, et al., Nature 394, 39 (1998).

    Article  CAS  Google Scholar 

  3. D. Kaczorowski, P. Rogl, and K. Hiebl, Phys. Rev. B: Condens. Matter 54, 9891 (1996).

    Article  Google Scholar 

  4. A. I. Tursina, Zh. M. Kurenbaeva, A. V. Gribanov, et al., J. Alloys Compd. 442, 100 (2007).

    Article  CAS  Google Scholar 

  5. Zh. M. Kurenbaeva, A. I. Tursina, E. V. Murashova, et al., J. Alloys Compd. 442, 86 (2007).

    Article  CAS  Google Scholar 

  6. E. V. Murashova, Zh. M. Kurenbaeva, A. I. Tursina, et al., J. Alloys Compd. 442, 89 (2007).

    Article  CAS  Google Scholar 

  7. E. V. Murashova, A. I. Tursina, Zh. M. Kurenbaeva, et al., J. Alloys Compd. 454, 206 (2008).

    Article  CAS  Google Scholar 

  8. J. F. Riecken, W. Hermes, B. Chevalier, et al., Z. Anorg. Allg. Chem. 633, 1094 (2007).

    Article  CAS  Google Scholar 

  9. R. Mishra, W. Hermes, U. Ch. Rodewald, et al., Z. Anorg. Allg. Chem. 634, 470 (2008).

    Article  CAS  Google Scholar 

  10. F. Tappe, W. Hermes, M. Eul, and R. Pottgen, Intermetallics 17, 1035 (2009).

    Article  CAS  Google Scholar 

  11. WinXPOW Software Manual (STOE&CIE, 2003).

  12. G. M. Sheldrick, SHELXS-97: Program for the Solution of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  13. G. M. Sheldrick, SHELXL-97: Program for the Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  14. J. Rodriguez-Carvajal, Physica B 192, 55 (1993).

    Article  CAS  Google Scholar 

  15. T. Roisnel and J. Rodriguez-Carvajal, Mat. Sci. Forum, 118 (2000).

  16. L. M. Gelato and E. Parthe, J. Appl. Crystallogr. 20, 139 (1987).

    Article  Google Scholar 

  17. J. Emsley, The Elements (Clarendon Press, Oxford, 1989; Mir, Moscow, 1993).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Vorob’evy gory, Moscow, 117234, Russia

    Zh. M. Kurenbaeva, A. I. Tursina, E. V. Murashova, S. N. Nesterenko & Yu. D. Seropegin

Authors
  1. Zh. M. Kurenbaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Tursina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Murashova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. N. Nesterenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. D. Seropegin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © Zh.M. Kurenbaeva, A.I. Tursina, E.V. Murashova, S.N. Nesterenko, Yu.D. Seropegin, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 2, pp. 256–260.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kurenbaeva, Z.M., Tursina, A.I., Murashova, E.V. et al. Synthesis and crystal structure of a new ternary intermetallic compound Ce16Ru8 + x In3 − x (0 < x < 1.0). Russ. J. Inorg. Chem. 56, 218–222 (2011). https://doi.org/10.1134/S003602361102015X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602361102015X

Keywords

Search

Navigation