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Phase equilibria in quasi-binary sections of the Tl-Sn-S system

  • Physicochemical Analysis of Inorganic Systems
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Abstract

Phase equilibria in quasi-binary sections of the Tl-Sn-S system: (I) Tl4SnS4-SnS, (II) Tl2SnS3-SnS, (III) S-Tl4SnS4, (IV) S-Tl2SnS3, (V) Tl-SnS, and (VI) Tl2S-SnS were studied by differential thermal analysis and X-ray powder diffraction. It was found that systems I and II are characterized by the eutectic type of interaction, the phase diagrams of systems III and IV are of the eutectic type with a degenerate eutectic at the sulfur melting point, and the phase diagram of system V is of the fourth type according to Roozeboom. Phase equilibria in system VI were specified.

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Authors and Affiliations

  1. Institute of Solid-State Physics and Chemistry, Uzhgorod, Ukraine

    T. A. Malakhovskaya-Rosokha

  2. Chair of Inorganic Chemistry, Uzhgorod National University, Uzhgorod, Ukraine

    M. Yu. Sabov, I. E. Barchii & E. Yu. Peresh

Authors
  1. T. A. Malakhovskaya-Rosokha
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  2. M. Yu. Sabov
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  3. I. E. Barchii
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  4. E. Yu. Peresh
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Corresponding author

Correspondence to T. A. Malakhovskaya-Rosokha.

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Original Russian Text © T.A. Malakhovskaya-Rosokha, M.Yu. Sabov, I.E. Barchii, E.Yu. Peresh, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 1, pp. 122–127.

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Malakhovskaya-Rosokha, T.A., Sabov, M.Y., Barchii, I.E. et al. Phase equilibria in quasi-binary sections of the Tl-Sn-S system. Russ. J. Inorg. Chem. 56, 118–123 (2011). https://doi.org/10.1134/S0036023611010189

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  • DOI: https://doi.org/10.1134/S0036023611010189

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