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Specific features of the structure of germanium(IV) complexes with polybasic acids

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Abstract

The specific features revealed in the structure of germanium(IV) compounds with ligands in the form of anions of polybasic acids (monoamine, diamine, and triamine complexones, i.e., hydroxyethylidene-diphosphonic and carboxylic acids) have been considered. The influence of the individuality of specific acids on the structure type (mononuclear, binuclear, trinuclear, hexanuclear, polynuclear), the coordination mode of monodentate ligands and donor atoms of polydentate ligands (terminal, bridging, chelating, chelating-bridging), and variants of the coordination of polydentate ligands, i.e., anions of polybasic acids, with metal atoms (germanium, rare-earth elements, copper, barium), as well as on the dependence of the Ge-O bond length on the individual nature of ligands (OH, H2O, O(oxo)) and donor atoms of polydentate ligands α- and β-O(carb), O(hydr), O(P)] and their function in the structure (terminal, bridging, chelating, chelating-bridging), has been analyzed using 28 homometallic and heterometallic complexes as an example.

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References

  1. I. I. Seifullina, E. E. Martsinko, L. Kh. Minacheva, A. G. Pesaroglo, and V. S. Sergienko, Ukr. Khim. Zh. 75(1), 3 (2009).

    CAS  Google Scholar 

  2. E. E. Martsinko, I. I. Seifullina, L. Kh. Minacheva, T. A. Syvak, and V. S. Sergienko, Zh. Neorg. Khim. 54(9), 1428 (2009) [Russ. J. Inorg. Chem. 54 (9), 1358 (2009)].

    CAS  Google Scholar 

  3. A. B. Ilyukhin, L. M. Shkol’nikova, I. I. Seifullina, and T. P. Batalova, Koord. Khim. 17(6), 795 (1991).

    CAS  Google Scholar 

  4. E. E. Martsinko, I. I. Seifullina, L. Kh. Minacheva, T. A. Shchur, and V. S. Sergienko, Zh. Neorg. Khim. 52(12), 2023 (2007) [Russ. J. Inorg. Chem. 52 (12), 1908 (2007)].

    CAS  Google Scholar 

  5. T. Mizuta, T. Yoshida, and K. Miyoshi, Inorg. Chim. Acta 165(1), 65 (1989).

    Article  CAS  Google Scholar 

  6. I. I. Seifullina, T. P. Batalova, E. V. Kolchinskii, and V. K. Bel’skii, Koord. Khim. 16(6), 773 (1990).

    CAS  Google Scholar 

  7. J. Zhu, T.-S. Huang, Y.-Q. Huang, et al., Chin. J. Struct. Chem. (Jiegou Huaxue) 14(1), 191 (1995).

    CAS  Google Scholar 

  8. M.-D. Chen, J. Zhu, and S.-Z. Hu, Main Group Met. Chem. 22, 105 (1999).

    CAS  Google Scholar 

  9. E. E. Martsinko, I. I. Seifullina, L. Kh. Minacheva, T. A. Shchur, and V. S. Sergienko, Zh. Neorg. Khim. 52(10), 1621 (2007) [Russ. J. Inorg. Chem. 52 (10), 1519 (2007)].

    CAS  Google Scholar 

  10. E. E. Martsinko, S. S. Smola, L. Kh. Minacheva, I. I. Seifullina, and V. S. Sergienko, Zh. Neorg. Khim. 54(7), 1103 (2009) [Russ. J. Inorg. Chem. 54 (7), 1041 (2009)].

    CAS  Google Scholar 

  11. V. S. Sergienko, L. Kh. Minacheva, I. I. Seifullina, and E. E. Martsinko, in Abstracts of Papers of the XXIV International Chugaev Conference on Coordination Chemistry, St. Petersburg, Russia, 2009 (St. Petersburg, 2009), p. 159.

  12. V. S. Sergienko, L. Kh. Minacheva, and A. V. Churakov, in Abstracts of Papers of the VI All-Russia Conference on Chemistry of Polynuclear Compounds and Clusters, Kazan, Russia, 2009 (Kazan, 2009), p. 160 (S-78).

  13. I. I. Seifullina, E. E. Martsinko, A. B. Ilyukhin, and V. S. Sergienko, Zh. Neorg. Khim. 43(10), 1628 (1998) [Russ. J. Inorg. Chem. 43 (10) 1509 (1998)].

    Google Scholar 

  14. V. S. Sergienko, G. G. Aleksandrov, I. I. Seifullina, and E. E. Martsinko, Kristallografiya 49(5), 876 (2004) [Crystallogr. Rep. 49 (5), 788 (2004)].

    Google Scholar 

  15. D. T. Cromer and D. Liberman, J. Chem. Phys. 53, 1891 (1970).

    Article  CAS  Google Scholar 

  16. A. B. Ilyukhin, L. M. Shkol’nikova, A. A. Poznyak, and S. S. Makarevich, Koord. Khim. 17(7), 918 (1991).

    CAS  Google Scholar 

  17. D. C. Finnen, A. A. Pinkerton, W. R. Dunham, R. H. Sands, and M. O. Funk, Inorg. Chem. (Washington) 30(20), 3960 (1991).

    CAS  Google Scholar 

  18. M. A. Porai-Koshits and T. N. Polynova, Koord. Khim. 10(6), 725 (1984).

    CAS  Google Scholar 

  19. L. Mafra, F. A. A. Paz, F.-N. Shi, J. Rocha, T. Trindade, C. Fernandez, A. Makal, K. Wozniak, and J. Klinowski, Chem.-Eur. J. 12, 363 (2006).

    Article  Google Scholar 

  20. E. E. Martsinko, I. I. Seifullina, V. S. Sergienko, and A. V. Churakov, Zh. Neorg. Khim. 50(6), 953 (2005) [Russ. J. Inorg. Chem. 50 (6), (2005)].

    CAS  Google Scholar 

  21. I. I. Seifullina, E. E. Martsinko, G. G. Aleksandrov, and V. S. Sergienko, Zh. Neorg. Khim. 49(6), 928 (2004) [Russ. J. Inorg. Chem. 49 (6), 844 (2004)].

    CAS  Google Scholar 

  22. L. Mafra, F. A. A. Paz, F.-N. Shi, R. A. Sa Ferreira, L. D. Carlos, T. Trindade, C. Fernandez, J. Klinowski, and J. Rocha, Eur. J. Inorg. Chem. 2006(23), 4741 (2006).

    Article  Google Scholar 

  23. V. S. Sergienko, Zh. Neorg. Khim. 45(6), 948 (2000) [Russ. J. Inorg. Chem. 45 (6), 850 (2000)].

    CAS  Google Scholar 

  24. N. M. Dyatlova, V. Ya. Temkina, and K. I. Popov, Complexones and Metal Complexonates (Khimiya, Moscow, 1988) [in Russian].

    Google Scholar 

  25. S. Nishigaki, H. Yoshioka, and K. Nakatsu, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 34, 875 (1978).

    Article  Google Scholar 

  26. A. L. Spek, J. Appl. Crystallogr. 36, 7 (2003).

    Article  CAS  Google Scholar 

  27. I. I. Seifullina, A. G. Pesaroglo, L. Kh. Minacheva, E. E. Martsinko, and V. S. Sergienko, Zh. Neorg. Khim. 51(12), 2010 (2006) [Russ. J. Inorg. Chem. 51 (12), 1892 (2006)].

    Google Scholar 

  28. I. I. Seifullina, A. G. Pesaroglo, L. Kh. Minacheva, E. E. Martsinko, and V. S. Sergienko, Zh. Neorg. Khim. 52(4), 550 (2007) [Russ. J. Inorg. Chem. 52 (4), 494 (2007)].

    CAS  Google Scholar 

  29. O. Seiler, C. Burschka, D. Schwahn, and R. Tacke, Inorg. Chem. 44(7), 2318 (2005).

    Article  CAS  Google Scholar 

  30. G. R. Willey, U. Somasunderam, D. R. Aris, and W. Errington, Inorg. Chim. Acta 315(2), 191 (2001).

    Article  CAS  Google Scholar 

  31. R. Tacke, J. Heerman, and M. Puim, Organometallics 16, 5648 (1997).

    Article  CAS  Google Scholar 

  32. A. G. Pesaroglo, E. E. Martsinko, L. Kh. Minacheva, et al., Zh. Neorg. Khim. 55 (2010) (in press) [Russ. J. Inorg. Chem. 55 (2010) (in press)].

  33. E. E. Martsinko, I. I. Seifullina, L. Kh. Minacheva, A. G. Pesaroglo, and V. S. Sergienko, Zh. Neorg. Khim. 53(11), 1814 (2008) [Russ. J. Inorg. Chem. 53 (11), 1694 (2008)].

    CAS  Google Scholar 

  34. E. E. Martsinko, A. G. Pesaroglo, L. Kh. Minacheva, et al., Zh. Neorg. Khim. 55 (2010) (in press) [Russ. J. Inorg. Chem. 55 (2010) (in press)].

  35. E. E. Martsinko, A. G. Pesaroglo, L. Kh. Minacheva, et al., Zh. Neorg. Khim. 55 (2010) (in press) [Russ. J. Inorg. Chem. 55 (2010) (in press)].

  36. E. L. Muetterties and L. J. Guggenberger, J. Am. Chem. Soc. 96, 1748 (1974).

    Article  CAS  Google Scholar 

  37. R. R. Holmes and J. A. Deiters, J. Am. Chem. Soc. 99, 3318 (1977).

    Article  CAS  Google Scholar 

  38. A. G. Shipov, E. P. Kramarova, T. P. Murasheva, Vad. V. Negrebetsky, S. Yu. Bylikin, A. A. Korlyukov, and Yu. I. Baukov, Izv. Akad. Nauk, Ser. Khim., No. 9, 2164 (2005) [Russ. Chem. Bull. 54 (9), 2233 (2005)].

  39. V. A. Efremov and A. Yu. Shashkov, Koord. Khim. 13(10), 1305 (1987).

    CAS  Google Scholar 

  40. G. Tringuier, M. Pelissier, B. Saint-Roch, and H. Lavassiere, J. Organomet. Chem. 214(2), 169 (1981).

    Article  Google Scholar 

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. S. Sergienko, L. Kh. Minacheva & A. V. Churakov

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  1. V. S. Sergienko
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  2. L. Kh. Minacheva
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  3. A. V. Churakov
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Sergienko, V.S., Minacheva, L.K. & Churakov, A.V. Specific features of the structure of germanium(IV) complexes with polybasic acids. Russ. J. Inorg. Chem. 55, 2001–2030 (2010). https://doi.org/10.1134/S0036023610130012

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