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Mononuclear nine-coordinate Na[SmIII(edta)(H2O)3] · 5H2O and one dimensional unlimited ladderlike eight-coordinate {[SmIII(Hpdta)(H2O)] · 2H2}O n Complexes: Synthesis and Structural Determination

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Abstract

The Na[SmIII(edta)(H2O)3] · 5H2O (H4edta = ethylenediamine-N,N,N′,N′-tetraacetic acid) and {[SmIII(Hpdta)(H2O)] · 2H2O} n (H4pdta = propylenediamine-N,N,N′,N′-tetraacetic acid) complexes were prepared with heat-refluxing and acidity-adjusting methods, respectively. And their composition and structures were determined by elemental analyses and single-crystal X-ray diffraction techniques. The Na[SmIII(edta)(H2O)3] · 5H2O complex shapes a mononuclear structure, and crystallizes in the orthorhombic crystal system with space group Fdd2. The central SmIII ion is nine-coordinated by one hexadentate edta ligand and three water molecules. The crystal data are as follows: a = 19.139(10) Å, b = 35.00(2) Å, c = 11.928(10) Å, V = 7989(9) Å3, Z = 16, D c = 2.014 g/cm3, μ = 3.046 mm−1, F(000) = 4848, R = 0.0439, and wR = 0.0941 for 3434 observed reflections with I ≥ 2σ(I). The SmN2O7 part in [SmIII(edta)(H2O)3]− complex anion forms a pseudo-monocapped square antiprismatic polyhedron. The {[SmIII(Hpdta)(H2O)] · 2H2O} n complex is prepared with protonated pdta ligand firstly, which forms one dimensional unlimited ladderlike eight-coordinated structure, and crystallizes in the monoclinic crystal system with space group P21/n. The central SmIII ion, in one construction unit, is coordinated by two nitrogen atoms from one hexadentate pdta ligand and six oxygens from the same pdta ligand, one water molecule and one carboxylic group of neighbour pdta ligand, respectively. The crystal data are as follows: a = 12.720(3) Å, b = 9.3800(19) Å, c = 14.420(3) Å, β = 96.11(3)°, V = 1710.7(6) Å3, Z = 2, D c = 1.971 g/cm3, μ = 3.492 mm−1, F(000) = 1004, R = 0.0225 and wR = 0.0607 for 3182 observed reflections with I ≥ 2σ(I). Otherwise, each part of SmN2O6 in {[SmIII(Hpdta)(H2O)] · 2H2O} complex segment adopts a pseudo-square antiprismatic polyhedron.

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References

  1. D. Alamelu, A. Sarkar, and S. K. Aggarwal, Talanta 77, 256 (2008).

    Article  CAS  Google Scholar 

  2. Q. Wang, Zh. Y. Yang, G. F. Qi, and D. D. Qin, Eur. Med. Chem. 44, 2425 (2009).

    Article  CAS  Google Scholar 

  3. T. M. Pana, J. Ch. Lina, M. H. Wub, and Ch. S. Lai, Bios. Bioelectron. 24, 2864 (2009).

    Article  Google Scholar 

  4. G. H. Zhong, X. W. Lei, and J. G. Mao, Phys. Rev. B: Condens., Matter 79, 9 (2009).

    Google Scholar 

  5. G. G. Marine, M. Christophe, and F. Karim, J. Eur. Urol. Suppl. 8, 114 (2009).

    Article  Google Scholar 

  6. E. R. Cardoso, H. Ashamalla, L. J. Weng, et al., J. Neurosurg.-Spine 10(4), 336 (2009).

    Article  Google Scholar 

  7. X. M. He, L. H. Zhang, and G. Zh. Chen, J. Alloy. Compd. 467(1–2), 366 (2009).

    Article  CAS  Google Scholar 

  8. H. F. Jiu, L. X. Zhang, G. D. Liu, and T. Fan, J. Lumin. 129(3), 317 (2009).

    Article  CAS  Google Scholar 

  9. T. Som and B. Karmakar, J. Lumin. 128(12), 1989 (2008).

    Article  CAS  Google Scholar 

  10. T. Mizuta, T. Yamamoto, K. Miyoshi, and Y. Kushi, Inorg. Chim. Acta 175, 121 (1990).

    Article  CAS  Google Scholar 

  11. M. M. Taqui Khan, D. Chatterjee, and R. R. Merchant, et al., Inorg. Chem. 31, 2711 (1992).

    Article  CAS  Google Scholar 

  12. V. S. Sergienko, L. M. Dikareva, M. A. Porai-Koshits, et al., Russ. J. Coord. Chem. 5, 920 (1979).

    CAS  Google Scholar 

  13. G. H. Y. Lin, J. D. Leggett, and R. M. Wing, Bull. Chem. Soc. Jpn. 53, 3189 (1980).

    Article  Google Scholar 

  14. K. Miyoshi, J. Wang, and T. Mizuta, Inorg. Chim. Acta 230, 119 (1995).

    Article  Google Scholar 

  15. K. Miyoshi, J. Wang, and T. Mizuta, Inorg. Chim. Acta 228, 165 (1995).

    Article  CAS  Google Scholar 

  16. S. Richards, B. Pedersen, J. V. Silverton, and J. L. Hoard, Inorg. Chem. 3, 27 (1964).

    Article  CAS  Google Scholar 

  17. M. Shimoi, Y. Orita, T. Uehiro, et al., Bull. Chem. Soc. Jpn. 53, 3189 (1980).

    Article  CAS  Google Scholar 

  18. M. D. Lind, B. Lee, and J. L. Hoard, J. Am. Chem. Soc. 87, 1611 (1965).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Liaoning University, Shenyang, 110036, China

    J. Wang, P. Hu, X. Chen, G. X. Han, R. Xu & X. D. Zhang

  2. Department of Pharmacy, Liaoning University, Shenyang, 110036, China

    B. Liu & L. Q. Zhang

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  1. J. Wang
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  2. P. Hu
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  3. B. Liu
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  4. X. Chen
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  5. L. Q. Zhang
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  6. G. X. Han
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  7. R. Xu
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  8. X. D. Zhang
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Original Russian Text © J. Wang, P. Hu, B. Liu, X. Chen, L.Q. Zhang, G.X. Han, R. Xu, X.D. Zhang, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 10, pp. 1660–1666.

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Wang, J., Hu, P., Liu, B. et al. Mononuclear nine-coordinate Na[SmIII(edta)(H2O)3] · 5H2O and one dimensional unlimited ladderlike eight-coordinate {[SmIII(Hpdta)(H2O)] · 2H2}O n Complexes: Synthesis and Structural Determination. Russ. J. Inorg. Chem. 55, 1567–1573 (2010). https://doi.org/10.1134/S003602361010013X

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  • DOI: https://doi.org/10.1134/S003602361010013X

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