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Synthesis and Structure of the bismuth complex [Ph3PrP] +4 [Bi4I16]4−

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Abstract

The complex [Ph3P] +4 [Bi4I16]4− · 2 Me2C=O (I) was synthesized by the reaction of triphenyl(propyl)phosphonium iodide with bismuth iodide in acetone. The crystal structure of complex I was determined by X-ray crystallography. It contains, in addition to solvent molecules, two types of crystallographically independent tetrahedral tetraphenyl(propyl)phosphonium cations and tetranuclear anions [Bi4I16]4− in a chair conformation with the bismuth atoms being in an octahedral coordination. The Bi-I distances in the anion vary within 2.8768(4)–3.2524(4) Å.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia

    V. V. Sharutin, I. V. Egorova, N. N. Klepikov & O. K. Sharutina

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  1. V. V. Sharutin
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  2. I. V. Egorova
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  3. N. N. Klepikov
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  4. O. K. Sharutina
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Original Russian Text © V.V. Sharutin, I.V. Egorova, N.N. Klepikov, O.K. Sharutina, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 7, pp. 1174–1177.

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Sharutin, V.V., Egorova, I.V., Klepikov, N.N. et al. Synthesis and Structure of the bismuth complex [Ph3PrP] +4 [Bi4I16]4− . Russ. J. Inorg. Chem. 55, 1103–1106 (2010). https://doi.org/10.1134/S003602361007017X

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  • DOI: https://doi.org/10.1134/S003602361007017X

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