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Synthesis, crystal and electronic structures, and thermodynamic characteristics of BaCe1 − x In x O3 − x/2 solid solutions

  • Synthesis and Properties of Inorganic Compounds
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Abstract

New perovskite oxide phases BaCe1 − x In x O3 − x/2 (x = 0.1–0.8) (space group Pbnm) have been synthesized. The unit cell volume of the resulting solid solutions monotonically decreases with an increase in the degree of substitution of indium for cerium due to the contraction of octahedra in perovskite blocks. The thermodynamic stability of the compound BaCe0.75In0.25O2.875 was studied by the solution calorimetry method, and barium cerates were shown to be thermodynamically stable with respect to binary oxides at room temperature. The structure of occupied and vacant states in BaCe1 − x In x O3 − x/2 was determined on the basis of X-ray emission, absorption, and photoelectron spectra, and the energy gap was estimated at ∼2 eV.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg, 620041, Russia

    T. I. Chupakhina & G. V. Bazuev

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    N. I. Matskevich

  3. Institute of Metal Physics, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 18, Yekaterinburg, 620219, Russia

    N. A. Ovechkina & V. R. Galakhov

  4. Universität Osnabrück-Fachbereich Physik, Osnabrück, Germany

    M. Raeckers & M. Neumann

Authors
  1. T. I. Chupakhina
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  2. N. I. Matskevich
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  3. G. V. Bazuev
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  4. N. A. Ovechkina
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  5. V. R. Galakhov
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  6. M. Raeckers
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  7. M. Neumann
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Original Russian Text © T.I. Chupakhina, N.I. Matskevich, G.V. Bazuev, N.A. Ovechkina, V.R. Galakhov, M. Raeckers, M. Neumann, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 7, pp. 1070–1077.

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Chupakhina, T.I., Matskevich, N.I., Bazuev, G.V. et al. Synthesis, crystal and electronic structures, and thermodynamic characteristics of BaCe1 − x In x O3 − x/2 solid solutions. Russ. J. Inorg. Chem. 55, 1002–1009 (2010). https://doi.org/10.1134/S003602361007003X

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  • DOI: https://doi.org/10.1134/S003602361007003X

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