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Synthesis of (2-hydroxo-5-chlorophenylaminoisonitrosoacetyl)phenyl ligands and their complexes: Spectral, thermal and solvent-extraction studies

  • Coordination Compounds
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Abstract

Four different types of new ligands Ar[COC(NOH)R] n (Ar=biphenyl, n = 1 H2L1; Ar=biphenyl, n = 2 H4L2; Ar=diphenylmethane, n = 1 H2L3; Ar=diphenylmethane, n = 2 H4L4; R=2-amino-4-chlorophenol in all ligands) have been obtained from 1 equivalent of chloroketooximes Ar[COC(NOH)Cl] n (HL1-H2L4) and 1 equivalent of 2-amino-4-chlorophenol (for H2L1 and H2L3) or 2 equivalent of 2-amino-4-chlorophenol (for H4L2 and H4L4). (Mononuclear or binuclear cobalt(II), nickel(II), copper(II) and zinc(II) complexes were synthesized with these ligands.) These compounds have been characterized by elemental analyses, AAS, infra-red spectra and magnetic susceptibility measurements. The ligands have been further characterized by 1H NMR. The results suggest that the dinuclear complexes of H2L1 and H2L3 have a metal:ligand ratio of 1:2; the mononuclear complexes of H4L2 and H4L4 have a metal:ligand ratio of 1:1 and dinuclear complexes H4L2 and H4L4 have a metal:ligand ratio of 2:1. The binding properties of the ligands towards selected transition metal ions (MnII, CoII, NiII, CuII, ZnII, PbII, CdII, HgII) have been established by extraction experiments. The ligands show strong binding ability towards mercury(II) ion. In addition, the thermal decomposition of some complexes is studied in nitrogen atmosphere.

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Authors and Affiliations

  1. Faculty of Science and Arts, Department of Chemistry, Süleyman Demirel University, 32260, Isparta, Turkey

    Fatma Karipcin, Bülent Dede & Mustafa Cengiz

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  1. Fatma Karipcin
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  2. Bülent Dede
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  3. Mustafa Cengiz
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Correspondence to Fatma Karipcin.

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Original Russian Text © Fatma Karipcin, Bülent Dede, Mustafa Cengiz, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 4, pp. 583–593.

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Karipcin, F., Dede, B. & Cengiz, M. Synthesis of (2-hydroxo-5-chlorophenylaminoisonitrosoacetyl)phenyl ligands and their complexes: Spectral, thermal and solvent-extraction studies. Russ. J. Inorg. Chem. 55, 530–540 (2010). https://doi.org/10.1134/S0036023610040078

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  • DOI: https://doi.org/10.1134/S0036023610040078

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