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Identification of the products of partial hydrolysis of silicon tetrafluoride by matrix isolation IR spectroscopy

  • Physical Methods of Investigation
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Abstract

Matrix isolation Fourier transform IR spectroscopy has been used for studying the products and mechanism of the silicon tetrafluoride reaction with water at various component ratios and reaction durations. Assignment of new bands in the spectrum confirms the earlier assumptions of first the formation of a molecular complex with water and later of trifluorosilanol, which finally condenses to give hexafluorodisiloxane.

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Authors and Affiliations

  1. Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorog, 603950, Russia

    P. G. Sennikov

  2. Lobachevskii State University, pr. Gagarina 25/3, Nizhni Novgorod, 603950, Russia

    S. K. Ignatov

  3. Alfred Wegener Institute for Polar and Marine Research, D-27570, Bremerhaven, Germany

    O. Schrems

Authors
  1. P. G. Sennikov
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  2. S. K. Ignatov
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  3. O. Schrems
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Additional information

Original Russian Text © P.G. Sennikov, S.K. Ignatov, O. Schrems, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 3, pp. 429–437.

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Sennikov, P.G., Ignatov, S.K. & Schrems, O. Identification of the products of partial hydrolysis of silicon tetrafluoride by matrix isolation IR spectroscopy. Russ. J. Inorg. Chem. 55, 413–420 (2010). https://doi.org/10.1134/S0036023610030198

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  • DOI: https://doi.org/10.1134/S0036023610030198

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